Visible-light induced FeCl₃-catalyzed reductive transamidation of N-acyl benzotriazoles with nitro compounds

Abstract

A mild and efficient visible-light promoted FeCl3-catalyzed reductive transamidation of N-acyl benzotriazoles with nitro compounds by PhSiH3 was developed.

Visible-light-induced Fe(iii)-promoted reduction amidation of 1,4,2-dioxazol-5-one

“…23 In 2024, Li's team reported the first visible-light induced iron-catalyzed reductive transamidation of N -acyl benzotriazoles with nitro compounds in the presence of silanes (Scheme 1c). 24…”