Visible Light-Induced Photocatalyst-Free Diastereoselective Iodosulfonylation of Cyclopropenes in Water

Abstract

This study presents a greener approach to the visible-light-induced micellar-catalyzed diastereoselective iodosulfonylation of cyclopropenes in a water medium. Remarkably, this process operates without a photocatalyst. Instead, it utilizes an electron-donor−acceptor complex formed between sulfonyl chloride and sodium iodide. This method is highly efficient and broadly applicable for both aromatic and aliphatic sulfonyl chlorides. Furthermore, this protocol enables the transformation of iodosulfonated cyclopropanes into sulfonated cyclopropenes, highlighting its substantial value as a versatile and powerful tool in synthetic chemistry.