Visible-light-induced reactions of methylenecyclopropanes (MCPs)

Abstract

Diverse visible-light-induced transformations for methylenecyclopropanes (MCPs) have been reported in recent years, attracting significant attention from synthetic chemists. As readily accessible strained molecules, MCPs have enough reactivity to selectively generate...

Fe3O4‐nanoparticle‐functionalized 3D‐printed injectable microgel

“…In our previous study, the flower-like Fe 3 O 4 is more conducive to enhancing bone regeneration. 26 In addition, the TEM images showed that the flower-like Fe 3 O 4 nanoparticles with a diameter of about 100 nm was self-assembled by smaller magnetic nanoparticles (about 20 nm), as shown in Figure 1b. Figure 1c revealed the morphology of PDA-coated nanoparticles.…”

“…The Fe 3 O 4 was synthesized via a simple solvothermal process as our previous study. 26 Briefly, the sodium dodecyl sulfate (SDS, 0.875 g, Keshi, China) and FeCl 3 Á6H 2 O (7 mmol, Keshi, China) were dissolved in ethylene glycol (EG, 70 mL, Keshi, China) with ultrasonication for 15 min. Then, 2-Aminoethanol (ETA, 5.25 mL, Keshi, China) was added into the above solution with vigorous stirring for 30 min.…”

Visible light-mediated hydrogen atom transfer and proton transfer for the conversion of (2-vinylaryl)methanol derivatives to aryl aldehydes or aryl ketones

“…Visible light-mediated chemical transformations have become a powerful tool in synthetic chemistry 1 and materials science 2 for the efficient construction of novel chemical skeletons under mild conditions in the last decade. On the basis of visible light-mediated reaction modes of single electron transfer (SET) and energy transfer (EnT), various robust organic transformations can be achieved under mild conditions, such as C–H bond functionalizations, 3 C–C and C–X (X = heteroatom) bond formations as well as their selective cleavage and the subsequent downstream functionalizations and so on.…”

An NIR-II-emitting type-I photosensitizer for efficient hypoxic tumor phototheranostics

“…) through an electron transfer process. 6 Profiting from the low O 2dependent characteristic, the achievement of type-I PDT is not easily influenced by O 2 concentration, providing a reliable approach for tumor therapy. 7 Besides, combined PDT and photothermal therapy (PTT) is regarded as an efficient method to achieve better anti-tumor outcomes.…”