The thermal-condensation method is widely used for the synthesis
of K-doped g-C3N4 photocatalysts,
but the presence of organic byproducts in the resultant products is
often overlooked in previous reports. Here, we demonstrated the universal
presence of organic byproducts in K-doped g-C3N4 synthesized by typical thermal condensation
of KOH/melamine, KOH/dicyandiamide, or KOH/urea. Taking the K-doped g-C3N4 photocatalysis for the degradation
of dimethyl phthalate as an example, the negative influence of the
organic byproducts on K-doped g-C3N4 photocatalysis was confirmed. Specifically, the organic byproducts
can be gradually dissolved into the photocatalytic system of K-doped g-C3N4 as new and stable pollutants.
Based on the solubility investigations on the byproducts in several
solvents, hot-water washing was demonstrated to be a relatively effective
approach to remove the organic byproducts from K-doped g-C3N4. The formation of organic byproducts
during the synthesis of K-doped g-C3N4 could be ascribed to the fact that the presence of K salts
in melamine, dicyandiamide, or urea molecules results in their insufficient
thermal condensation into expected g-C3N4. The present work provides objective information about
the K-doped g-C3N4 photocatalysts
and reminds researchers about the influence of the organic byproducts
on the applications of the other impurity-doped g-C3N4 photocatalysts.