Lomefloxacin hydrochloride (LMFX) and sodium salicylate
(SS) are
important targets for real-time detection due to their widespread
uses in daily life; accurate and portable monitoring of LMFX and SS
is crucial for human health concerns accordingly. Developing a precise
and smart platform for determination of the above analytes remains
a significant challenge. Herein, a high-sensitivity platform incorporating
a luminescence electrospinning film, self-designed smart-phone app,
and portable 3D printing device has been developed to identify LMFX
and SS. In this work, two heterometallic coordination polymers with
two-dimensional layer structures have been synthesized based on 2,2′-oxidiacetic
acid ligand (H2oda), namely, [LnPb(oda)2(CH3COO)]
n
[Ln = Eu (IMU-1); Tb (IMU-2)]. IMU-1 and IMU-2 were ratio-dependent luminescence probes, which could selectively
and sensitively sense with LMFX and SS, respectively. Additionally,
the synthesized electrospinning films incorporating IMU-1 and IMU-2 were employed to identify LMFX and SS. Both
films could rapidly photograph and color-capture through a portable
3D printing device, along with a self-designed smart-phone app that
enabled convenient and quick determination of the concentrations of
the above analytes. Remarkably, the mechanism exploration indicated
that electron transfer from ligands to analytes affected the antenna
effect and further utilized the intrinsic luminescence of analytes
along with the luminescence quenching of Ln3+ ions. Furthermore,
a strategy for constructing ratio-based fluorescent probes by exploiting
the luminescence of analytes and Ln3+ ions in host coordination
polymers is proposed. This work provides a new insight by combining
luminescence probes, portable devices, and a smart-phone app for real-time
detection of drugs and food additives.