The impact formation of the (D + , X) bound-exciton in n-GaAs at 4.2 K during an impact ionization avalanche under an applied pulse voltage has been investigated. The bright PL-pattern observed by applying the pulse voltage characterizes well the formation of a current density filament. The observations of the bright PL-pattern give a quite new result concerning the electron-impact formation process of the excitons bound to the ionized donors (D + , X).At low temperatures, high-purity semiconductors behave like insulators, because a large part of the shallow impurities is charge-neutral and only a few charge carriers can be mobile. By applying an electric field of a few V/cm, the neutral shallow impurities are completely ionized due to an impact ionization avalanche, causing the negative differential resistivity (NDR) in the current−voltage characteristic. By the low-temperature impurity breakdown, a current density filament can be formed between the ohmic contacts [1, 2]. The current density filament has been typically observed as a photoluminescence (PL) quench-pattern [3].By the PL method, Aoki and Fukui [4−6] have investigated the nucleation process of a current density filament [4] and also the nonlinear dynamics of the filament during the current instability under magnetic fields in n-GaAs [1,5,6]. Very recently, the author has found, that the PL pattern image under a short pulse voltage can be seen as a bright pattern inside the filament or along the filament boundaries in a n-GaAs Corbino disc [7,8], where the anomalous brightening of the PL intensity was seen under a very weak photoexcitation density. In this paper, the anomalous PL brightening during the impact ionization avalanche of the neutral shallow donors is discussed in detail, and a new interpretation of the impact formation of the excitons bound to ionized donors is given.All of the measurements were done at 4.2 K, using a high-purity n-GaAs sample with a thickness of the epitaxial layer of 21 µm grown on a semi-insulating substrate. The electron density and the electron mobility were n = 6.23 × 10 13 cm −3 and µ = 1.23 × 10 5 cm 2 /Vs at 77 K, respectively. The area of the sample surface was approximately (6.0 × 6.0) mm 2 , on which the disk-shaped ohmic contacts were formed (see Fig. 1). The sample surface was very weakly excited by a 35 mW (or 20 mW) He−Ne laser beam, where the laser beam was spread over the whole sample surface by using a spatial filter and strongly attenuated by using neutral density filters. The photon density was J p ≈ 63 µW/cm 2 . The spatiotemporal