A facile approach for improving color purity is explored
by the
introduction of an angle-robust selective absorber (ARSA) into bottlebrush
block copolymer (BBCP)-based one-dimensional (1D) photonic crystals
(PCs). The BBCPs of poly[(3-(12-(cis-5-norbornene-exo-2,3-dicarboximido)dodecanoylamino)propyl POSS)-block-(norbornene-graft-styrene)], P
x
(x = 1–4), with
ultrahigh molecular weights (M
n ∼
2260 kDa) and low dispersities (D̵ ∼
1.07) are synthesized by ring-opening metathesis polymerization. The
1D PCs of the lamellar structure are fabricated by self-assembly of
the BBCP with different periodicities for full color-generation (blue,
green, and red). The optically tailored substrate (i.e., ARSA) is
used to modulate the spectral line shape with selective absorption
in the near-infrared range. Optical simulation proposes the optimized
1D PC structures on the ARSA, and it provides the reproducibility
of the predictable color. The simulated structures are well matched
with the experimental results, verifying the enhancement of color
saturation even at various incident angles (0–70°).