Out-of-plane
Ga2Se3 nanowires are grown by
molecular beam epitaxy via Au-assisted heterovalent exchange reaction
on GaAs substrates in the absence of Ga deposition. It is shown that
at a suitable temperature around 560 °C the Au-decorated GaAs
substrate releases Ga atoms, which react with the incoming Se and
feed the nanowire growth. The nanowire composition, crystal structure,
and morphology are characterized by Raman spectroscopy and electron
microscopy. The growth mechanism is investigated by X-ray photoelectron
spectroscopy. We explore the growth parameter window and find an interesting
effect of shortening of the nanowires after a certain maximum length.
The nanowire growth is described within a diffusion transport model,
which explains the nonmonotonic behavior of the nanowire length versus
the growth parameters. Nanowire shortening is explained by the blocking
of Ga supply from the GaAs substrate by thick, in-plane worm-like
Ga2Se3 structures, which grow concomitantly
with the nanowires, followed by backward diffusion of Ga atoms from
the nanowires down to the substrate surface.