14The Snowdon caldera of North Wales is host to base metal sulfide-bearing veins and stockworks, 15 mineralized breccias, disseminated sulfides, and localized zones of semi-massive to massive sulfide, 16 with subordinate magnetite-rich veins. The late Ordovician host volcanic sequence accumulated in a 17 shallow marine, back-arc environment in the Welsh Basin, which forms part of the Avalon Zone of 18 the British and Irish Caledonides. New field evidence, sulfur isotopes, and U-Pb dating indicate that 19 the Snowdon mineralization is genetically and temporally related to Late Ordovician magmatism and 20 caldera formation. It is interpreted to represent volcanogenic pipe-style sulfide mineralization, 21 resulting from focused hydrothermal fluids moving along caldera-related faults and simultaneous 22 dispersal of fluids through the volcaniclastic pile. Sulfur isotope data suggest that, whilst a limited 23 contribution of magmatic S cannot be ruled out, thermochemical reduction of contemporaneous 24Ordovician seawater sulfate was the dominant mechanism for sulfide production in the Snowdon 25 system, resulting in a mean value of about 12‰ in both the host volcanic strata and the mineralized 26 veins. Despite the tectonic setting being prospective for VMS deposits, strata-bound sulfide 27 accumulations are absent in the caldera. This is attributed to the shallow water depths, which 28 promoted boiling and the formation of sub-seafloor vein-type mineralization. Furthermore, the 29 tectonic instability of the caldera and the high energy, shallow marine environment would have 30 limited preservation of any seafloor deposits. The new U-Pb dates for the base (454.26 ± 0.35 Ma) 31 and top (454.42 ± 0.45 Ma) of the host volcanic rocks, indicate that the Snowdon magmatic activity 32 was short lived, which is likely to have limited the duration and areal extent of the ore-forming system. 33 2 The absence of massive sulfide mineralization is consistent with the general paucity of economic 34 VMS deposits in the Avalon Zone. Despite the highly prospective geological setting this study further 35 illustrates the importance of volcanic facies mapping and associated paleo-environmental 36 interpretations in VMS exploration. 37