Cantilever probes for scanning probe microscopy (SPM) applications are fabricated in almost any case from (100) silicon wafers. Although the probes show excellent mechanical properties which make silicon cantilevers appropriate for topography imaging by scanning force microscopy (SFM), modern SPM applications force the search for novel materials with specific material properties which would be of advantage in SPM. In this paper several concepts for SPM probes are described which make use of specific properties of gallium arsenide, diamond and various metals. Different sensor concepts, e.g. in the tip integrated Schottky diode, coplanar waveguide lines integrated on a cantilever probe, etc., are introduced. They are designed for imaging of thermal, electrical, and optical sample surface properties exploiting the unique properties of the above-mentioned materials.Since the invention of scanning force microscopy (SFM) by Binnig et al. in 1986 [1], scanning probe microscopy (SPM) has been demonstrated to be a intriguing tool for highresolution imaging of various physical surface properties [2]. In particular, the cantilever probe concept introduced for SFM has proven to be the most versatile and flexible one available so far. A prerequisite for SFM is the fabrication of probes with reproducible properties, e.g. resonance frequency, force constant, tip shape, and radius of curvature of the tip [3]. Until today the material used for probe fabrication has been almost exclusively (100)-oriented Si (or silicon nitride) because of the well-established micromachining techniques known from semiconductor technology.The most important aspect regarding the potential of SPM is the possibility to integrate various sensors in a single probe. This allows us to image additional physical quantities besides the surface topography. To achieve this aim, novel probe concepts have to be developed and realized by reproducible technological processes. Although the mechanical properties of silicon are quiet excellent with respect to SFM, in modern applications of SPM other probe properties, e.g. electrical, thermal, optical, magnetic, etc., are decisive. For this reason novel materials with specific physical properties have to be considered to optimize probe sensitivity as well as to find new applications.In the first section of the paper it is demonstrated that not only Si, but also GaAs, diamond, and thin metal filmsmaterials with unique physical properties -are appropriate materials. Technological processes will be described which allow batch processing of these materials for probe fabrication. In the second part of the paper the material properties are considered -a significant point for the development of novel active and passive SPM probes.We report on the design and micromachined fabrication of near-field probes for high-frequency scanning electrical force microscopy (HFSEFM), scanning thermal microscopy (SThM), and scanning near-field optical microscopy (SNOM). Probe concepts and fabrication processes presented include the possibilit...