Voltammetry of thermally prepared ruthenium oxide films and flux detection at the electrolyte interface

Barbu, A.; Plichon, V.

doi:10.1016/s0013-4686(96)00240-x

Cited by 11 publications

(3 citation statements)

References 20 publications

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“…43 The technique has also been used to study the ion exchange ruthenium oxides. 44 2.2.2 Inorganic complex films. PBD techniques have also been utilized to study the redox coupled ion exchange in mixed salts (ferric ferrocyanide (Prussian blue)), 45 cupric ferrocyanide, 46 indium ferrocyanide 47 and lutetium diphthalocyanine.…”

Section: Other Oxidesmentioning

confidence: 99%

Ion exchange at the electrode/electrolyte interface studied by probe beam deflection techniques

Barbero

2005

Phys. Chem. Chem. Phys.

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Probe beam deflection (PBD) techniques are a set of in situ electrochemical methods based on the measurement of refractive index gradients in front of the electrode/electrolyte interface. Here, the details of the techniques are described. First, the theory of potential step chronodeflectometry and pulse voltadeflectometry is discussed. Later, different numerical procedures used for data processing and/or simulation of cyclic voltadeflectometry experiments are described. Then, an overview is performed of the techniques use to study electrochemical systems. The systems described are limited to surface species in binary electrolytes, where a clear interpretation of the data is possible. Among the systems studied are: surface reactions on solid electrodes, electrochromic oxides, conducting polymers, redox polymers, double layer charging in nanostructured carbons and ion exchange in layer-by-layer self assembled multilayers. It is shown that PBD techniques have been able to ascertain the effect of different factors on ion exchange: anion size, pH, solvent, film composition, covalent modification, etc. The capability of the techniques to perform fast measurements was also used with success to find out kinetic effects on the ion exchange.

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Section: Other Oxidesmentioning

confidence: 99%

Ion exchange at the electrode/electrolyte interface studied by probe beam deflection techniques

Barbero

2005

Phys. Chem. Chem. Phys.

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“…IrOx is used for applications in a wide range of fields, including pH-sensing [116], electrochromic devices and optical information storage, chlorine or oxygen evolution, neural stimulation [117], field emission cathodes, and advanced memory technology. More recently it is gaining renewed interest as electrode material for supercapacitors [118].…”

Section: Iridium Oxidementioning

confidence: 99%

“…If only sputtered iridium oxide films (SIROFs) are considered, already the sputter parameters like substrate temperature, oxygen pressure and vacuum pressure are of great influence in the electrochemical behavior [119,125,126]. CV diagrams measured with SIROFs exhibit a typical 'featureless' or capacitor-like shape [118,119,127], compared to AIROFs [117,128,129].…”

Section: Iridium Oxidementioning

confidence: 99%

Miniaturized electrochemical cells for applications in drug screening and protein cleavage

Odijk¹

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Application of Probe Beam Deflection Techniques to the Study of Surface-Confined Electrochemical Systems

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Barbero

2012

Monographs in Electrochemistry

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Voltammetry of thermally prepared ruthenium oxide films and flux detection at the electrolyte interface

Cited by 11 publications

References 20 publications

Ion exchange at the electrode/electrolyte interface studied by probe beam deflection techniques

Ion exchange at the electrode/electrolyte interface studied by probe beam deflection techniques

Miniaturized electrochemical cells for applications in drug screening and protein cleavage

Application of Probe Beam Deflection Techniques to the Study of Surface-Confined Electrochemical Systems

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