Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures

Kinart, Cezary M.; Nowak, Katarzyna; Kinart, Wojciech J.

doi:10.1016/j.jct.2004.09.014

Cited by 18 publications

(8 citation statements)

References 23 publications

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“…This was accomplished by utilizing the Karl Fisher coulometer (756KF Coulometer Metrohm). Experimental values of density, speed of sound, and refractive index of the pure liquids are compared in Table at (293.15, 298.15, 303.15, 313.15, and 323.15) K, and these values show good agreement with the published results. ,− …”

Section: Methodssupporting

confidence: 66%

Thermodynamic, Ultrasonic, and Transport Study of Binary Mixtures Containing 2-(2-Methoxyethoxy)ethanol and Alcohols at (293.15–323.15) K

et al. 2020

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Binary mixtures of 2-(2-methoxyethoxy)ethanol and alcohols were characterized in terms of the existence of intermolecular interactions at different temperatures (293.15, 303.15, 313.15, and 323.15) K and at pressure p = 0.1 MPa. The alcohols were methanol, ethanol, propan-1-ol, propan-2-ol, butan-1-ol, and butan-2-ol. The study was based on the measurements of densities, speeds of sound, and refractive indices over the entire range of mixture compositions. The obtained data were used to calculate various thermodynamics/ deviation properties: excess molar volume, isentropic compressibility, deviation in isentropic compressibility, and deviation in refractive indices. Excess/deviation properties were fitted to the Redlich−Kister equation to estimate the coefficients. The standard deviation of the fit was calculated between the predicted and the experimental quantities to ensure the accuracy of the experimental data.

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Section: Methodssupporting

confidence: 66%

Thermodynamic, Ultrasonic, and Transport Study of Binary Mixtures Containing 2-(2-Methoxyethoxy)ethanol and Alcohols at (293.15–323.15) K

et al. 2020

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“… a ρ, density; u , speed of sound; α P , isobaric thermal expansion coefficient; κ S , adiabatic compressibility; κ T , isothermal compressibility; C V , isochoric heat capacity; and C P , isobaric heat capacity. b Ref . c Ref . d Ref . e Ref . f Ref . g Ref . h Ref . i Ref . j Ref . k Ref . l Ref . m Ref . n Ref . o Ref . p Ref . …”

Section: Methodsmentioning

confidence: 99%

Thermodynamics of Mixtures Containing Alkoxyethanols. Part XXVI. Densities, Excess Molar Volumes, Speeds of Sound at (293.15, 298.15, and 303.15) K, and Isentropic or Isothermal Compressibilities at 298.15 K for 2-Methoxyethanol + Alkoxyethanol or 2-Propoxyethanol + Dibutylether Systems

et al. 2008

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Densities, ρ, and speeds of sound, u, for the systems 2-methoxyethanol (2ME) + 2-ethoxyethanol (2EE), or + 2-butoxyethanol (2BE), or + 2-(2-methoxyethoxy)ethanol (22MEE) and for the 2-propoxyethanol (2PE) + dibutylether (DBE) mixture have been measured at (293.15, 298.15, and 303.15) K and atmospheric pressure using a vibrating-tube densimeter and sound analyzer (Anton Paar model DSA-5000). The ρ and u values were used to calculate excess molar volumes, V E, at the mentioned temperatures, molar excess heat capacities at constant volume, C V E, at 298.15 K, and deviations from the ideal behavior at 298.15 K of the thermal expansion coefficient, Δα P , and of the isentropic and isothermal compressibilities, Δκ S and Δκ T , respectively. In DBE systems, H E(molar excess enthalpy) and V E decrease with the size of the 2-alkoxyethanol. In 2ME + alkoxyethanol mixtures, these magnitudes increase with the size of the second compound, although their values depend on the number of etheric atoms of this component.

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“…We have studied previously the nature and type of intermolecular interactions in binary liquid mixtures containing alkoxyalcohols in terms of the mixing parameters such as excess molar volume, excess molar refractivity, deviations in relative permittivity, deviations in viscosity, and deviations in isentropic compressibility [1][2][3][4][5][6]. The 2-ethoxyethanol (EE), 2-(2-ethoxyethoxy)ethanol (DEE), 2-{2-(2-ethoxyethoxy)ethoxy}ethanol (TEE), and polyethylene glycol 300 (PEG-300) have been used in the present studies.…”

Section: Introductionmentioning

confidence: 99%

Excess molar volumes of the binary mixtures of polyethylene glycol 300 with ethoxyethanols at various temperatures

Kinart

Ćwilińska

et al. 2006

The Journal of Chemical Thermodynamics

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Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures

Cited by 18 publications

References 23 publications

Thermodynamic, Ultrasonic, and Transport Study of Binary Mixtures Containing 2-(2-Methoxyethoxy)ethanol and Alcohols at (293.15–323.15) K

Thermodynamic, Ultrasonic, and Transport Study of Binary Mixtures Containing 2-(2-Methoxyethoxy)ethanol and Alcohols at (293.15–323.15) K

Thermodynamics of Mixtures Containing Alkoxyethanols. Part XXVI. Densities, Excess Molar Volumes, Speeds of Sound at (293.15, 298.15, and 303.15) K, and Isentropic or Isothermal Compressibilities at 298.15 K for 2-Methoxyethanol + Alkoxyethanol or 2-Propoxyethanol + Dibutylether Systems

Excess molar volumes of the binary mixtures of polyethylene glycol 300 with ethoxyethanols at various temperatures

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