VUV photodesorption of molecular hydrogen from the hydrogenated silicon(111) surface

Wetterauer, U.; Pusel, A.; Hess, Peter

doi:10.1016/s0009-2614(98)01375-x

Cited by 3 publications

(2 citation statements)

References 21 publications

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“…(11) and (12) over all configurations ͕͖ and assume translational invariance from here on, i.e., in the limit L → ϱ there are no privileged sites in the lattice. Then we have ͗ i ͘ = ͗ j ͘ = ͑t͒ and ͗ i i+1 ͘ = ͗ j j+1 ͘ = C 2 ͑t͒ for all i, j, where C 2 ͑t͒ is the two-particle correlation.…”

Section: Theoretical Analysismentioning

confidence: 99%

“…For example, in ultrahigh vacuum CVD for the case of Si(100), molecular hydrogen forms by recombination at localized monohydride dimers ͑H-Si-Si -H͒ [6,9,10]. Wetterauer et al [11] found that this pathway is supplemented by single atom photodesorption from a hydrogenated Si(111) surface. In plasma-enhanced CVD growth of hydrogenated amorphous and microcrystalline silicon, which are emergent alternatives to crystalline Si in many electronic devices, impinging hydrogen gas atoms recombine with Sihydrides but also with bonded hydrogen surface atoms to form H 2 .…”

Section: Introductionmentioning

confidence: 99%

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Spatial fluctuations and anomalous reaction order in a reactive scheme involving a cooperative full desorption

2004

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Anomalous reaction rates have been found in the hydrogen desorption of H-terminated surfaces in semiconductor epitaxy, with a reaction order shifting from two to one, or even taking fractional values. We analyze the issue in terms of a cooperative full desorption (CFD) reaction A+A--k3-->S+S , coupled to an adsorption reaction S--k1-->A and an alternative desorption route A--k2-->S . Steady state properties of the three-step reactive scheme are analyzed in a one-dimensional lattice in the absence of diffusion. Microscopic Monte Carlo simulations show anomalous spatial distributions of reactants in the stationary state: depending on the reaction rate constants of the overall scheme, either a local "aggregation" or a local "dispersion" of A -particles is observed. The CFD reaction itself is well described by a fractional order kinetics that takes into account these anomalies and that depends on the kinetic rate constants of the overall adsorption-desorption reaction mechanism. The problem is addressed with an analytical approach for the active neighborhood of a reactant, which provides a closed expression of the reaction order as a function of the kinetic parameters. This approach is in excellent agreement with numerical simulations. Spatial correlations, as well as fluctuation correlations, are also formalized in terms of the kinetic constants. We discuss the results in the context of the hydrogen evolution reaction on silicon surfaces.

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Section: Theoretical Analysismentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Spatial fluctuations and anomalous reaction order in a reactive scheme involving a cooperative full desorption

2004

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Non-adiabatic and ultrafast dynamics of hydrogen adsorbed on silicon

Kołasiński

2004

Current Opinion in Solid State and Materials Science

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Sc₂C₂@C₈₀ Rather than Sc₂@C₈₂: Templated Formation of Unexpected C_2v(5)-C₈₀ and Temperature-Dependent Dynamic Motion of Internal Sc₂C₂ Cluster

et al. 2011

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Unambiguous X-ray crystallographic results of the carbene adduct of Sc(2)C(82) reveal a new carbide cluster metallofullerene with the unexpected C(2v)(5)-C(80) cage, that is, Sc(2)C(2)@C(2v)(5)-C(80). More interestingly, DFT calculations and NMR results disclose that the dynamic motion of the internal Sc(2)C(2) cluster depends strongly on temperature. At 293 K, the cluster is fixed inside the cage with two nonequivalent Sc atoms on the mirror plane, thereby leading to C(s) symmetry of the whole molecule. However, when the temperature increases to 413 K, the (13)C and (45)Sc NMR spectra show that the cluster rotates rapidly inside the C(2v)(5)-C(80) cage, featuring two equivalent Sc atoms and weaker metal-cage interactions.

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VUV photodesorption of molecular hydrogen from the hydrogenated silicon(111) surface

Cited by 3 publications

References 21 publications

Spatial fluctuations and anomalous reaction order in a reactive scheme involving a cooperative full desorption

Spatial fluctuations and anomalous reaction order in a reactive scheme involving a cooperative full desorption

Non-adiabatic and ultrafast dynamics of hydrogen adsorbed on silicon

Sc₂C₂@C₈₀ Rather than Sc₂@C₈₂: Templated Formation of Unexpected C_2v(5)-C₈₀ and Temperature-Dependent Dynamic Motion of Internal Sc₂C₂ Cluster

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VUV photodesorption of molecular hydrogen from the hydrogenated silicon(111) surface

Cited by 3 publications

References 21 publications

Spatial fluctuations and anomalous reaction order in a reactive scheme involving a cooperative full desorption

Spatial fluctuations and anomalous reaction order in a reactive scheme involving a cooperative full desorption

Non-adiabatic and ultrafast dynamics of hydrogen adsorbed on silicon

Sc2C2@C80 Rather than Sc2@C82: Templated Formation of Unexpected C2v(5)-C80 and Temperature-Dependent Dynamic Motion of Internal Sc2C2 Cluster

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Sc₂C₂@C₈₀ Rather than Sc₂@C₈₂: Templated Formation of Unexpected C_2v(5)-C₈₀ and Temperature-Dependent Dynamic Motion of Internal Sc₂C₂ Cluster