2008
DOI: 10.1016/j.chemphys.2008.08.009
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VUV photophysics and dissociative photoionization of pyrimidine, purine, imidazole and benzimidazole in the 7–18eV photon energy range

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Cited by 57 publications
(87 citation statements)
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References 101 publications
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“…Ionization-induced fragmentation of different biomolecules has been studied quite extensively using various techniques: ion-and electron bombardment, [2][3][4][5][6] electrospray ionization, 7,8 and photoionization [9][10][11] to name few. Gas phase studies have mostly concentrated on small free molecules, due to the difficulties in introducing larger molecules into the gas phase intact.…”
Section: Introductionmentioning
confidence: 99%
“…Ionization-induced fragmentation of different biomolecules has been studied quite extensively using various techniques: ion-and electron bombardment, [2][3][4][5][6] electrospray ionization, 7,8 and photoionization [9][10][11] to name few. Gas phase studies have mostly concentrated on small free molecules, due to the difficulties in introducing larger molecules into the gas phase intact.…”
Section: Introductionmentioning
confidence: 99%
“…Extensive experimental efforts [5][6][7][8][9][10][11] have been made since the 1970's to measure the photoelectron properties of DNA and RNA bases. Meanwhile, theoretical calculations on their ionization potentials and electron affinities have been carried out using density-functional theory (DFT) and high-level quantum chemistry methods 8,10,[12][13][14][15] .…”
mentioning
confidence: 99%
“…The loss of HCN moieties, which is thermodynamic stable, was reported to be a general feature in fragmentation processes of nitrogen heterocycles [37,42]. Mass 54 amu is assigned to the HCN fragment including the 13 C or 15 N isotope.…”
Section: Pyrimidinementioning
confidence: 99%