Silver nanostructures are among the most important platforms
for
developing efficient plasmonic materials, and edges and/or spikes
in such structures can produce highly localized surface plasmons,
resulting in dramatic electromagnetic field enhancement. In addition,
if the enhanced field and/or localized surface plasmons were to be
visualized in a periodic structure with long-range order, then this
data would be invaluable for plasmonics researchers and engineers.
Herein, we present an optical technique for plasmon mapping in the
silver nanohole array and edge (nano-sawtooth) structures over large
areas (∼10 μm). Plasmon mapping via two-dimensional fluorescence
intensity enhancement quantification with submicrometer spatial resolution
revealed high enhancement factors of up to 200 for the nano-sawtooth
structure. These measurements were performed alongside atomic force
microscopy, scanning electron microscopy, and finite-difference time-domain
calculations, and the enhancement mechanism was investigated. Furthermore,
the silver nanohole array and nano-sawtooth structures were fabricated
using straightforward and cost-effective processes.