Abundant carbonate is a characteristic feature of most Archean mesothermal Au-Ag vein deposits, but the source of the C is controversial. For Superior Province deposits collectively, the maximum variation of average SI3c values is from -9.0 2 0 . 7 %~ ( l a , n = 19; Darius) to -0.6 + 1 . 6 %~ ( l u , n = 7; Cochenour-Willians), and limiting SI3c values are -13.6 and + 1.3%0. At the deposit scale, Fe dolomites in nongraphitic lithologies are for the most part isotopically uniform, where S13c .2 2 0.3 (Bousquet), -5.4 ? 0.9 (Lamaque), and -5.3 + 0 . 5 %~ (Hasaga): the restricted individual ranges of SI3C values imply a corresponding uniformity to the ambient temperature and s~~c~~ of the ore-forming fluids.Within individual deposits, small systematic variations of S '~C carbonate arise from (i) interaction of hydrothermal fluids with carbonaceous rocks, (ii) immiscible separation of COz + CH,, or (iii) Rayleigh fractionation effects. Positive shifts in 613c result from buffering of the fluid to lower Eh by reaction with reduced C, whereas negative shifts reflect partial isotopic equilibration between I3C-depleted C (613c = -26%0) and aqueous hydrothermal C species. Transient immiscibility of C 0 2 + CH4 acts to precipitate carbonates enriched relative to the main population of Fe dolomites. The SI3c values of carbonates in unmineralized alteration halos (-2.2 2 I .~% G , n = 42) at the McIntyre deposit are enriched in 13c relative to the main gold-bearing vein systems (SI3c = -3.2 + 0.3%~): the enrichment is attributed to a Rayleigh fractionation accompanying progressive consumption of C 0 2 as hydrothermal fluids infiltrate laterally from veins into wall rocks. Fe dolomite and calcite are variably enriched in "0 with respect to equilibrium quartz-carbonate fractionations for ambient temperatures of 270"-340°C. Carbonate 6180 values diminish in an irregular manner with depth, converging on values of -1 1 %~ (Fe dolomite, 6800 ft (2073 m), McIntyre). Variable degrees of oxygen-isotope disequilibrium represent overprinting of carbonates by post-Archean brines in the Canadian Shield. Synvolcanic vesicle calcite in three groups of metabasalts (SI3c = -4.3 f 2.1; -2.8 2 1.5; -2.7 2 1.3%0) and calcite in two groups of clastic sediments (-6.4 + 1.8; -4.6 ? 2.5%0) remote from deposits are systematically depleted of 13C relative to average Precambrian limestones (-0 & I%o), owing to the involvement of COz derived from I3c-depleted organic matter. Consequently, calcite in greenstone belt supracrustal rocks is not restricted to approximately 0 %~. The total spread of average SI3C~, dol values (-9.0 2 0.7 to -0.6 + 0 . 6 %~) in the Au deposits, which goes in hand with a geographical provinciality in 0 -,Sr-, and Pb-isotope compositions of the ore-forming fluids, is too large to be accounted for by mantle C 0 2 (-6 2 2%0) or magmatic C 0 2 (-6 * 2 %~) alone but rather is interpreted as reflecting generation of hydrothermal fluids in crustal or subcreted rocks heterogeneous in terms of the distribution of 13c-enriched (carbonat...