Previous studies show that the surface roughness of the sidewall generated by deep X-ray lithography (DXL) is a function of the photon energy of X-rays. Present study demonstrates and reveals the ideas of controlling surface roughness by tuning irradiation photon energy on the sidewall using the developing temperature. The ideas are resulted from two observations (1) X-rays of higher energy induce photoelectrons of higher energy in the resist and the corresponding scattering distance is nearly a square function of electron energy [1], and (2) high-energy X-rays are expected to induce more surface roughness and this effect has been observed by different laboratory [2].
IntroductionThe synchrotron radiation is a white light source containing radiation ranging from IR to hard X-rays. The 1.5 GeV synchrotron Taiwan Light Source (TLS) with a characteristic wavelength of 0.58 nm provides main radiation of the soft X-rays. The micromachining beamline at the TLS selects the X-rays from 0.2 to 0.4 nm for the DXL and the ultra-deep X-ray lithography (UDXL) [3]. As X-rays penetrate the resist, the spectra are moving from low-energy to high-energy region due to the faster absorption of low-energy X-rays [4]. The developed sidewall of constant dosage as shown in Fig. 1 is mainly formed by the competition of two effects, i.e. attenuation and diffraction [1,5]. The first effect to be discussed is the wavelength-dependent attenuation in the vertical direction [4]. The intensity decays exponentially with coefficient nearly proportional to the cubic power of the wavelength. Therefore, low-energy X-rays decay faster than high-energy X-rays. The average energy of X-rays increases as the X-rays penetrate in depth. The second effect of the Fresnel diffraction deals mainly in the horizontal direction. As illustrated in Fig. 1, the X-ray mask is placed on top of photoresist with a gap g. Absorbers on the mask block the X-ray irradiation at the opaque region. However, the X-rays have a gray exposure at the opaque edge due to the diffraction. Higher-energy X-rays are less diffractive. The gray exposure is again wavelength-dependent. The diffracted intensity spectrum is nearly a square function of the wavelength. Present study utilizes these two contradictory phenomena to control the surface roughness of the sidewall by changing the average photon-energy.
ExperimentThe experiments are designed to understand the relation between the surface roughness and the induced photoelectron energy using the spectrum-shift along the penetration path. Figure 2 illustrates the schematic drawing of the experimental setup. Two freestanding thin PMMA sheets [3] of 200 microns in thickness are irradiated at our 'micromachining beamline' with an optic cubic prism (beam splitter) as mask. After the irradiation, the sample was immediately placed in the developing bath of the G-G developer [3] for 2 h, and therefore developed from both sides. The development should stop at the surface of threshold dosage determined by the developing temperature of G-G developer....