The
cracking resistance performance of an asphalt binder is a significant
factor affecting the durability of asphalt pavements, and wax-based
warm mix additives are devoted to improving the crack resistance of
asphalt pavements. However, different components of wax-based warm
mix additives (Fischer–Tropsch (F–T)-, fatty acid amide
(FAA)-, polyethylene (PE)-, and linear aliphatic hydrocarbon (LAH)-based
waxes) have different effects on the cracking resistance performance
of the asphalt binder. Therefore, the optimum component of additives
was determined by the combination of a microscopic method and a macroscopic
test. The average carbon numbers of four additives were determined
by a high-temperature gas chromatography (HTGC) test. The multiple
stress creep recovery (MSCR), double-edge-notched tension (DENT),
and extended bending beam rheological (ExBBR) tests were used to characterize
the macroscopic performance of a modified asphalt binder. The F–T
wax with long-chain molecules improved the high-temperature performance
and lowered the degree of acceleration of thermoreversible aging.
The FAA, PE, and LAH waxes with short-chain molecules enhanced the
ductile fracture resistance performance. Therefore, the average carbon
number as the optimum component of wax-based additives was recommended
as C40 to C60.