An increase in temperature
of up to 2 °C occurs when the amount
of CO
2
reaches a range of 450 ppm. The permanent use of
mineral oil is closely related to CO
2
emissions. Maintaining
the sustainability of fossil fuels and eliminating and reducing CO
2
emissions is possible through carbon capture and storage
(CCS) processes. One of the best ways to maintain CCS is hydrate-based
gas separation. Selected type T1-5 (0.01 mol % sodium dodecyl sulphate
(SDS) + 5.60 mol % tetrahydrofuran (THF), with the help of this silica
gel promotion was strongly stimulated. A pressure of 36.5 bar of
CO
2
is needed in H
2
O to investigate the CO
2
hydrate formation. Therefore, ethylene glycol monoethyl ether
(EGME at 0.10 mol %) along with SDS (0.01 mol %) labeled as T1A-2
was used as an alternative to THF at the comparable working parameters
in which CO
2
uptake of 5.45 mmol of CO
2
/g of
H
2
O was obtained. Additionally, it was found that with
an increase in tetra-
n
-butyl ammonium bromide (TBAB)
supplementation of CO
2
, the hydrate and operating capacity
of the process increased. When the bed height was reduced from 3
cm to 2 cm with 0.1 mol % TBAB and 0.01% SDS (labelled as T3-2) in
fixed bed reactor (FBR), the outcomes demonstrated a slight expansion
in gas supply to 1.54 mmol of CO
2
/g of H
2
O at
working states of 283 K and 70 bar. The gas selectivity experiment
by using the high-pressure volume analysis through hydrate formation
was performed in which the highest CO
2
uptake for the employment
of silica contacts with water in fuel gas mixture was observed in
the non-IGCC conditions. Thus, two types of reactor configurations
are being proposed for changing the process from batch to continuous
with the employment of macroporous silica contacts with new consolidated
promoters to improve the formation of CO
2
hydrate in the
IGCC conditions. Later, much work should be possible on this with
an assortment of promoters and specific performance parameters. It
was reported in previous work that the repeatability of equilibrium
moisture content and gas uptake attained for the sample prepared by
the highest rates of stirring was the greatest with the CIs of ±0.34
wt % and ±0.19 mmol of CO
2
/g of H
2
O respectively.
This was due to the amount of water occluded inside silica gel pores
was not an issue or in other words, vigorous stirring increased the
spreadability. The variation of pore size to improve the process can
be considered for future work.