Improving oil production
for high-salinity reservoirs using polymer
flooding is challenging due to chemical and mechanical degradations.
This study developed two biodegradable biopolymers based on graft
copolymerization of guar gum (GG) with two different co-monomers,
which are acrylamide (Am) and 2-acrylamido-2-methylpropane sulfonic
acid (AMPS), and cross-linked by
N,N
′-methylene
bisacrylamide (MBA) to face these challenges. The newly synthesized
guar gum-based hydrogels, GG-
g
-poly(Am-AMPS) (GH)
and GG-
g
-poly(Am-AMPS)/Biochar (GBH composite), were
evaluated as potential candidates for enhanced oil recovery (EOR)
under high-salinity conditions. Fourier transform infrared (FTIR)
spectroscopy and thermogravimetric analysis (TGA) of the synthesized
hydrogels were investigated, and their rheological properties were
measured at room temperature. Both GH and GHB display a shear-thinning
performance. In polymer flooding experiments, guar gum hydrogel (GH)
and guar gum/biochar composite hydrogel (GHB) showed a remarkable
influence on delaying the water breakthrough and proved to be effective
biopolymers for enhanced oil recovery in high-salinity reservoirs.
At the optimum concentration of 5 g/L, GH flooding achieved maximum
oil recoveries of 70.53 and 72.11% in secondary and tertiary recovery
processes, respectively. Meanwhile, the waterflooding process achieved
an ultimate oil recovery of 58.42%. GHB flooding at optimum concentration,
2 g/L, increased the amount of oil recovery by 8.95% in tertiary recovery
compared to waterflooding. Furthermore, GH (5 g/L) and GHB (2 g/L)
slightly enhanced the rock water wettability as confirmed by contact
angle measurements for GH and the relative permeability saturation
curves for GH and GHB.