Osmotic coefficients, φ, electrical conductance data, Λ, and refractive indices, n D , of aqueous solutions of the ionic liquid, 1-pentyl-3-methylimidazolium chloride [PnMIm]Cl have been measured at T = (298. 15, 308.15, 318.15, and 328.15) K. Measurements of osmotic coefficients were carried out by the vaporpressure osmometry method (VPO). Osmotic coefficient values show that ion-solvent interactions are stronger at lower temperature. The osmotic coefficients were correlated to the Pitzer-ion interaction and modified NRTL (MNRTL) models. From these data, mean molal activity coefficients, γ ±, and excess Gibbs free energies, G E , have been calculated. Electrical conductance data have been applied for determination of association constants, K a , and limiting molar conductances, Λ 0 , using the low concentration chemical model (lcCM). Calculated ion-association constant, K a , values show that ion-association effects increase at high temperatures which is in agreement with osmotic coefficient results. Experimental results of refractive indices for the binary system are reported, and have been fitted by a polynomial expansion.