Water adsorption properties of a Sc(<scp>iii</scp>) porous coordination polymer for CO<sub>2</sub> capture applications

Álvarez, J. Raziel; Peralta, Ricardo A.; Balmaseda, J.; González‐Zamora, Eduardo; Ibarra, Ilich A.

doi:10.1039/c5qi00176e

Cited by 56 publications

(46 citation statements)

References 45 publications

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“…The positive effect of water inside the pores was confirmed also for MIL‐53(Al), NOTT‐400, Mg‐CUK‐1 and CAU‐10 …”

Section: Introductionsupporting

confidence: 55%

“…[65] An even higher increase was achieved for the NOTT-401 MOF (Scandium-thiophene-2,5-dicarboxylic acid), reaching a 3.2-fold uptake increase under 5 % RH. [66] The positive effect of water inside the pores was confirmed also for MIL-53(Al) [67] , NOTT-400, [68] Mg-CUK-1 [69] and CAU-10. [70] For microporous MOFs only limited quantities of preadsorbed H 2 O can increase the carbon dioxide capture.…”

Section: Confinement Of Solvents Within Mofs Poresmentioning

confidence: 53%

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Strategies to Enhance Carbon Dioxide Capture in Metal‐Organic Frameworks

Piscopo

Loebbecke

2020

ChemPlusChem

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The dramatic increase of atmospheric CO2 concentration is responsible for a fast and potentially unpredictable global climate change. Therefore, the implementation of negative carbon technologies such as direct air capture (DAC) is needed. Metal–organic frameworks (MOFs) have the potential to perform CO2 DAC and achieve unprecedented performances. Herein strategies to improve the CO2 capture efficiency of MOFs and their potential implementation in real applications are discussed. Three main categories of targeted modifications to the frameworks are usually performed to enhance the CO2 uptake capacity and adsorption selectivity: 1) modifications to the metal unit; 2) modifications to the linker unit; 3) confinement of solvents within MOFs. The synthesis of MOF composites using other porous materials as support is also a useful method to improve the CO2 capture performances. Another approach involves the synthesis of amine‐functionalized MOFs that can chemically bind carbon dioxide.

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“…The positive effect of water inside the pores was confirmed also for MIL‐53(Al), NOTT‐400, Mg‐CUK‐1 and CAU‐10 …”

Section: Introductionsupporting

confidence: 55%

Section: Confinement Of Solvents Within Mofs Poresmentioning

confidence: 53%

Strategies to Enhance Carbon Dioxide Capture in Metal‐Organic Frameworks

Piscopo

Loebbecke

2020

ChemPlusChem

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“…[1] Particularly, the effect of water vapor addition has been studied in different materials, especially at low temperatures. [3,[11][12][13][14] Table 1 summarizes the total CO 2 capture capacities and cyclability conditions for different alkaline ceramics in the presence of water vapor as well as other materials in dry and wet conditions. [2,4, Among alkaline ceramics, Li 5 AlO 4 and Li 8 SiO 6 present high NOTT-401 30 9.9 wt% --Wet [37] Ni 3 (BTC) 2 40 2.5 --Dry [38] chemisorption capacities, which have been attributed to high Li/M (M ¼ Al or Si) atomic ratio.…”

Section: Introductionmentioning

confidence: 99%

“…[12] Such behavior is also presented in the low-temperature range, where CO 2 capture capacity of some hydrotalcites is improved in the presence of water. [12,47,48] MOFs interaction with CO 2 is normally weak; hence, these materials begin to desorb CO 2 at T > 30 C. In some cases, it has been shown that small amounts of water increase CO 2 adsorption due to confinement effects induced by H 2 O, [14,37] but in the majority of these cases, water addition has a detrimental effect as these materials are saturated with water. [9,32] The CO 2 capture capacity of amines is increased in the presence of water, which is associated with the formation of bicarbonate and carbonate species.…”

Section: Introductionmentioning

confidence: 99%

“…Typically, a postcombustion flue gas contains N 2 (76%–77%), CO 2 (12.5%–12.8%), water vapor (6.2%), O 2 (4.4%), and traces of other gases, such as CO, NO x , and SO 2 . Particularly, the effect of water vapor addition has been studied in different materials, especially at low temperatures . Table summarizes the total CO 2 capture capacities and cyclability conditions for different alkaline ceramics in the presence of water vapor as well as other materials in dry and wet conditions .…”

Section: Introductionmentioning

confidence: 99%

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CO₂—H₂O Capture and Cyclability on Sodium Cobaltate at Low Temperatures (30–80 °C): Experimental and Theoretical Analysis

2019

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Sodium cobaltate (NaCoO2) is analyzed for the CO2 cyclic carbonation–decarbonation process at low temperatures (30–80 °C) with relative humidity (RH) values between 0% and 80%, using water vapor as a catalytic intermediate. The presence of H2O clearly enhances the CO2 capture at T < 100 °C, compared with dry conditions, where the amount of CO2 captured increases as a function of RH. These improvements are attributed to the formation of NaHCO3 and Na2CO3 during carbonation. In the case of NaHCO3, water vapor becomes a part of carbonation, favoring reactivity. After the carbonation analysis, the decarbonation process is analyzed using a N2 flow, where results evidence that only NaHCO3 decomposition takes place at low temperatures, producing NaOH and CO2. This result indicates that NaCoO2 can be partially regenerated, suggesting a possible CO2 cyclic carbonation. CO2 carbonation–decarbonation tests are performed, confirming the cyclic capacity and stability. Moreover, the NaCoO2 sample is modified by adding different transition metals (Fe, Cu, and Ni) to improve CO2—H2O sorption under similar physicochemical conditions. Results indicate that Fe‐containing samples present the best properties. Finally, the effect of CO2 partial pressure on NaCoO2 and Fe‐containing samples is analyzed using similar RHs.

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Metal–Organic Frameworks for Water Harvesting and Concurrent Carbon Capture: A Review for Hygroscopic Materials

et al. 2023

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As water scarcity becomes a pending global issue, hygroscopic materials prove a significant solution. Thus, there is a good cause following the structure–performance relationship to review the recent development of hygroscopic materials and provide inspirational insight into creative materials. Herein, traditional hygroscopic materials, crystalline frameworks, polymers, and composite materials are reviewed. The similarity in working conditions of water harvesting and carbon capture makes simultaneously addressing water shortages and reduction of greenhouse effects possible. Concurrent water harvesting and carbon capture is likely to become a future challenge. Therefore, an emphasis is laid on metal–organic frameworks (MOFs) for their excellent performance in water and CO2 adsorption, and representative role of micro‐ and mesoporous materials. Herein, the water adsorption mechanisms of MOFs are summarized, followed by a review of MOF's water stability, with a highlight on the emerging machine learning (ML) technique to predict MOF water stability and water uptake. Recent advances in the mechanistic elaboration of moisture's effects on CO2 adsorption are reviewed. This review summarizes recent advances in water–harvesting porous materials with special attention on MOFs and expects to direct researchers’ attention into the topic of concurrent water harvesting and carbon capture as a future challenge.

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Water adsorption properties of a Sc(iii) porous coordination polymer for CO₂ capture applications

Cited by 56 publications

References 45 publications

Strategies to Enhance Carbon Dioxide Capture in Metal‐Organic Frameworks

Strategies to Enhance Carbon Dioxide Capture in Metal‐Organic Frameworks

CO₂—H₂O Capture and Cyclability on Sodium Cobaltate at Low Temperatures (30–80 °C): Experimental and Theoretical Analysis

Metal–Organic Frameworks for Water Harvesting and Concurrent Carbon Capture: A Review for Hygroscopic Materials

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Water adsorption properties of a Sc(iii) porous coordination polymer for CO2 capture applications

Cited by 56 publications

References 45 publications

Strategies to Enhance Carbon Dioxide Capture in Metal‐Organic Frameworks

Strategies to Enhance Carbon Dioxide Capture in Metal‐Organic Frameworks

CO2—H2O Capture and Cyclability on Sodium Cobaltate at Low Temperatures (30–80 °C): Experimental and Theoretical Analysis

Metal–Organic Frameworks for Water Harvesting and Concurrent Carbon Capture: A Review for Hygroscopic Materials

Contact Info

Product

Resources

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Water adsorption properties of a Sc(iii) porous coordination polymer for CO₂ capture applications

CO₂—H₂O Capture and Cyclability on Sodium Cobaltate at Low Temperatures (30–80 °C): Experimental and Theoretical Analysis