With the rise of smart textiles, fibers/textiles-based
sensors
are being applied in various situations, such as healthcare, green
energy, and environmental monitoring. The field of health monitoring
mainly involves the detection of human secretions (such as sweat,
saliva, urine, and excrement). Among them, sweat is extensive and
closely related to human health, so it is receiving more and more
attention. Various sensors are used for sweat detection, but fiber/textile-based
flexible sensors have unique advantages and thus have emerged as an
important branch. So, this Review aims to 1) explain the physiological
mechanism of sweating and metabolites; 2) introduce the advantages
of fibers/textiles as the substrate of sweat sensors; 3) outline different
kinds of fibers/textiles-based flexible sweat sensors (enzymatic biosensors,
non-enzymatic biosensors, ion-selective sensors, and others) and explain
their working principle; 4) summarize the applications of such sensors
in different fields (physical condition monitoring, power supply,
drug monitoring, mental state monitoring, etc.). Moreover, the opportunities
and challenges of flexible fiber/textile-based sweat sensors will
also be discussed. This Review will help promote the diversified development
of sweat sensors, which is significant for manufacturing advanced
sweat detection and diagnostic systems.