2014
DOI: 10.1016/j.tetlet.2013.12.005
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Water inclusion as a trigger for modulation of anthracene arrangement and fluorescence emission of organic salt

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Cited by 11 publications
(3 citation statements)
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“…This study proposes a 9phenylanthracenyl group as a versatile intramolecular template to align the target fluorophores depending on the presence of organic solvent and counter ions. [26][27][28] Provided that the fluorophore and anthracene parts are properly modified, this dyad design holds a great potential for sophisticated controlling of the self-assembly of fluorophores, for example, a fluorescence probe with complete fluorescence quenching via intermolecular photoinduced electron transfer, sensitive colorimetric probes, and near-infrared absorbing materials for the energy field application Furthermore, 1 O 2 is a particularly important reactive oxygen species in photodynamic therapy and can react with anthracene derivatives, resulting in the endoperoxide formation. Concerning that SiR-An exhibited a good cell permeability (Fig.…”
Section: Tmr-anmentioning
confidence: 99%
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“…This study proposes a 9phenylanthracenyl group as a versatile intramolecular template to align the target fluorophores depending on the presence of organic solvent and counter ions. [26][27][28] Provided that the fluorophore and anthracene parts are properly modified, this dyad design holds a great potential for sophisticated controlling of the self-assembly of fluorophores, for example, a fluorescence probe with complete fluorescence quenching via intermolecular photoinduced electron transfer, sensitive colorimetric probes, and near-infrared absorbing materials for the energy field application Furthermore, 1 O 2 is a particularly important reactive oxygen species in photodynamic therapy and can react with anthracene derivatives, resulting in the endoperoxide formation. Concerning that SiR-An exhibited a good cell permeability (Fig.…”
Section: Tmr-anmentioning
confidence: 99%
“…For this purpose, we focused on a phenylanthracenyl group that can construct diverse crystal structures from the slipped-stacked column to herringbone structures upon the addition of solvents, organic and inorganic salts. [26][27][28] It was hypothesized that a combination of phenylanthracene and charged fluorophore moieties can trigger unusual fluorophore assemblies apart from the H-dimer, typical aggregates in the aqueous solution. Among the various fluorophores, rhodamine derivatives have been chosen because of (i) their similar size and planarity to anthracene and (ii) electron-deficient characteristics as compared to the electron-rich anthracene moiety, which further assist the intermolecular interaction.…”
mentioning
confidence: 99%
“…Additionally, the excitation spectra of the crystals were similar to that of Linear- t Amyl , indicating that luminescence from Linear-Me is monomeric emission and that from Linear- c Hex (Form 1) is excimer emission. 57–61 Linear-Et (Form 1) and Linear- i Pr showed more red-shifted light-blue emission with the emission maximum wavelength ( λ em_max ) at 467 and 468 nm with a lifetime ( τ em ) of 8.51 and 12.6 ns, respectively (Fig. 5b and e).…”
Section: Resultsmentioning
confidence: 98%