“…Although our experimental setup favor the hydrothermal alteration as responsible for the formation of the smectite clay, also the role of chemical weathering also suggested in different regions on Mars cannot be excluded (e.g., [8,16,17,81,83]). Several studies proposed geomorphological evidence based on numerous and well-preserved valley networks and channels, and many impact craters that show deltas, lakes and sedimentary layers (e.g., [81,84,85]), coupled with a hydrated mineralogy, which suggest an ancient water-rock interaction (e.g., [8]), which may have contributed to the neogenesis of smectite under environmental meteoric conditions. Specifically, the chemical weathering processes in the Gale and Gusev craters on Mars where the alkaline basalts outcrop, induced the formation of smectite in analogies with the Etna basaltic sample (see Section 3.1) Although our experimental setup favor the hydrothermal alteration as responsible for the formation of the smectite clay, also the role of chemical weathering also suggested in different regions on Mars cannot be excluded (e.g., [8,16,17,81,83]).…”