Molecular Water Oxidation Catalysis 2014
DOI: 10.1002/9781118698648.ch9
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Water Oxidation by Co‐Based Oxides with Molecular Properties

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Cited by 7 publications
(9 citation statements)
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“…The Tafel slope of crystalline Co 3 O 4 was found to be very similar compared with the one of electrodeposited Co oxide films, which exhibit ≥60 mV dec −1 in 0.1 M KP i . (refs 26 , 30 , 45 ). We note that catalytic activity and Co oxide redox behaviour showed very good stability ( Supplementary Figs 3–9 ).…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The Tafel slope of crystalline Co 3 O 4 was found to be very similar compared with the one of electrodeposited Co oxide films, which exhibit ≥60 mV dec −1 in 0.1 M KP i . (refs 26 , 30 , 45 ). We note that catalytic activity and Co oxide redox behaviour showed very good stability ( Supplementary Figs 3–9 ).…”
Section: Resultsmentioning
confidence: 99%
“…A well-known X-ray amorphous OER electrocatalyst is the so-called cobalt-phosphate catalyst, herein denoted as CoCat 2 23 24 25 26 27 28 29 30 , which is catalytically active in neutral phosphate-containing electrolyte and excels by self-repair properties 29 . The CoCat films consist of layer fragments of ∼12–14 octahedrally coordinated (mainly) Co 3+ ions connected via di-μ 2/3 -oxo bridges 23 24 25 .…”
mentioning
confidence: 99%
“…36,38 CoCat has been the subject of numerous mechanistic studies. 39,40 Bediako et al studied the dependence of current on overpotential (Tafel plots) with different buffer concentrations and conditions, decoupling the catalytic reaction from the proton−electron hopping inside the film. 13 A subsequent work focused on CV analysis to estimate a lower limit for the catalytic rate and proposed that catalysis is limited by the diffusion of the proton accepting base.…”
Section: ■ Introductionmentioning
confidence: 99%
“…Amorphous Co oxide films prepared by electrodeposition in neutral solution (CoCat) were introduced by Kanan and Nocera . The catalyst resting state is composed of a Co II –Co III mixture, with Co IV species appearing at potentials relevant to catalytic water oxidation. ,, The Co oxidation state change is coupled to release of a proton to the buffer species in solution and represents a pre-equilibrium preceding the turnover limiting step, which has been proposed to be the formation of an oxygen–oxygen bond. ,, The catalyst is formed by molecular fragments containing 14–19 Co atoms; , water oxidation takes place in the bulk of the film , at the periphery of the CoOx fragments. , CoCat has been the subject of numerous mechanistic studies. , Bediako et al studied the dependence of current on overpotential (Tafel plots) with different buffer concentrations and conditions, decoupling the catalytic reaction from the proton–electron hopping inside the film . A subsequent work focused on CV analysis to estimate a lower limit for the catalytic rate and proposed that catalysis is limited by the diffusion of the proton accepting base .…”
Section: Introductionmentioning
confidence: 99%
“…Here, we investigate the role of potassium ions in a cobalt-based, volumeactive [8] catalyst material which contains K + as well as phosphate ions. [22] This oxyhydroxide material, in the following denoted as CoCat, has been especially well investigated [23][24][25][26][27][28][29][30] and can serve as a model system in mechanistic investigations on water oxidation (OER) by non-noble metal materials in the environmentally friendly neutral-pH regime. [7,[31][32][33] Central open questions regarding the role of potassium ions are:…”
Section: Introductionmentioning
confidence: 99%