Water Physico-Chemical Indicators and Metal Assessment of Teceu Lake and the Adjacent Groundwater Located in a Natura 2000 Protected Area, NW of Romania

Abstract

This study closely analyzes the water quality dynamics of Teceu Lake, situated in a Natura 2000 protected area in Romania. The research investigates seasonal variations and interconnections with groundwater, assessing various ecological impacts. The main physico-chemical indicators of water, such as electrical conductivity (EC), dissolved oxygen (DO), oxygen saturation (OS), temperature, pH, turbidity, ammonium concentration (NH4+), nitrates (NO3−), nitrites (NO2−), orthophosphates (PO43−), water hardness, alkalinity (A), and chlorides (Cl−), were measured over the January–December 2022 period. Metal concentrations for both major metals (Na, K, Ca, Mg, Al) and trace metals (Li, Ga, Fe, Mn, Pb, Cu, Zn, Ni, Ti, Mo, Sr, Ba) were assessed. The evolution of the physico-chemical indicators revealed an increase in nutrient compounds (ammonium and phosphates) during the spring and autumn months. The EC values ranged from 180–444 μS/cm for the lake and 1575–2480 μS/cm for groundwater. The pH values (7.12–7.96) indicated a slightly alkaline environment. DO levels (6.79–11.21 mg/L) indicated good water quality. Chlorides exceeded levels in drinking water in some instances. Water hardness varied due to pH, temperature, and atmospheric pressure. Metal composition revealed diverse levels of aluminum, barium, nickel, copper, zinc, and manganese, which carries implications for environmental and human health. The water quality index (WQI) score, which is based on major ions, indicated that 93% of the groundwater samples were classified as excellent and good for drinking. WQI, based on the main physico-chemical indicators, revealed that 79.17% of the Teceu Lake-water samples and 41.66% of the groundwater samples gathered were classified as good quality; the difference indicated poor quality, especially in autumn. Q- and R-mode cluster analyses revealed distinct clusters for seasonal months and sampling points, suggesting shared sources and geological influences. Notable connections between physico-chemical indicators and metal content were identified, emphasizing the need for a tailored conservation strategy. Correlation analyses highlighted both positive and negative relationships between metal pairs. Understanding these parameters is vital for water resource management and preserving biodiversity in the region. The results of this study are important for monitoring pollution in Lake Teceu and might prompt local communities and authorities to take measures to reduce and prevent pollution.

Evaluating Groundwater Metal and Arsenic Content in Piatra, North-West of Romania

“…These variations could be attributed to geological factors, such as differing soil compositions or proximity to potential contamination sources, influencing the conductivity of the groundwater in each well. A previous study [46] on another well within the region registered much higher values (1575-2480 µS/cm), attributed to the interaction with aquifer rocks. EC serves as evidence of salt content in water, and the ingestion of water with elevated EC levels may contribute to a range of health issues, including but not limited to cancer, diarrhea, hepatitis, and gastroenteritis, impacting vital organs such as the heart, kidneys, and stomach [48].…”

“…This could be explained by more intense agricultural practices in the former compared to the latter, coupled also with the heavy practice in Romanian countryside involving the application of animal manure. Teceu locality is also in close proximity to Piatra town, and water analysis on a well in Teceu [46] revealed values for ammonium, chlorides, nitrates, and phosphates within the legal limits for potable water. However, it should be stated that [46] only analyzed one well in that specific town, which would be a limitation for stating the pollution levels for wells in the area.…”

“…Teceu locality is also in close proximity to Piatra town, and water analysis on a well in Teceu [46] revealed values for ammonium, chlorides, nitrates, and phosphates within the legal limits for potable water. However, it should be stated that [46] only analyzed one well in that specific town, which would be a limitation for stating the pollution levels for wells in the area.…”

“…The water quality index (WQI) is an approach to assessing the quality of diverse water samples, consolidating various indicators of water composition into a singular representative value that conveys comprehensive information about water quality [29,40,[42][43][44][45][46]. The WQI method was used to assess the overall quality of groundwater samples based on a weighted arithmetic technique, considering 23 indicators of water quality: EC, pH, turbidity, NH 4 + , NO 3 − , PO 4 3− , and the metals: Li, Na, K, Ca, Mg, Ba, Sr, Al, Fe, Mn, Cr, Cu, Ni, Pb, Zn, and As.…”

“…Human health risk assessment by groundwater consumption was established according to the method described in the literature [46,[54][55][56], by computing the chronic daily intake of water contaminants, CDI (mg/kg•day), hazard quotients (HQ) for each water contaminant, and the hazard index (HI). Nutrients such as NH 4 + and NO 3 − , metals (Al, Sr, Ba, Fe, Mn, Cr, Cu, Ni, Pb, and Zn), and As were considered to compute the hazard index, HI.…”