2001
DOI: 10.1016/s0040-6090(01)00901-4
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Water-repellent coating films on glass prepared from hydrolysis and polycondensation reactions of fluoroalkyltrialkoxylsilane

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Cited by 71 publications
(33 citation statements)
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“…So generally the acquirement of hydrophobic surface is out of two approaches [39][40][41][42][43][44][45][46]: chemical modification to surface or roughening the surface. But most researches about hydrophobic films did not aim to improve the hydrophobicity of optical film.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…So generally the acquirement of hydrophobic surface is out of two approaches [39][40][41][42][43][44][45][46]: chemical modification to surface or roughening the surface. But most researches about hydrophobic films did not aim to improve the hydrophobicity of optical film.…”
Section: Introductionmentioning
confidence: 99%
“…Generally, with fluoroalkyltrialkoxylsilane (FAS) as hydrophobic precursor, the chemical modification to solid surface was used to form hydrophobic films by several studies [31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46]. Nakagawa [31], Hong [32] and Aksmatsu et al [46] synthesized fluoroalkyl-modified SiO 2 sols through acid-catalyzed hydrolysis of FAS in ethanol, and prepared hydrophobic films.…”
Section: Introductionmentioning
confidence: 99%
“…Recently, with the increasing demands toward functionality of materials that cannot withstand high temperatures, such as textiles and plastics, the control of surface wettability via low-temperature processing is particularly significant. Surface modification with hydrophobic properties using the sol-gel method has been investigated during recent years [8]. Although D DAVID PUBLISHING simple sol-gel reactions usually result in the formation of amorphous materials, self-organization of organosilane molecules offers an opportunity to create ordered hybrid materials with hydrophobic properties [9].…”
Section: Hdtmsmentioning
confidence: 99%
“…However, the preparation of silica sols has been limited to use silicon alkoxides such as tetraethoxysilane (TEOS) as precursor in the sol-gel synthesis [7][8][9][10][11][12][13][14][15][16]. This chemical method using TEOS has some advantages, such as convenience in controlling size distribution.…”
Section: Introductionmentioning
confidence: 99%
“…The common chemicals used were fluoroalkylsilanes (FAS) [9][10][11][12][13][14][15][16]. It is true that fluorochemicals have extremely low surface free energy; however, such compounds are high cost and have a potential risk for human health and for environment [17,18].…”
Section: Introductionmentioning
confidence: 99%