Hydrochemical (major and some minor constituents), stable isotope (dD H2O and d 18 O H2O ; d 13 C TDIC total dissolved inorganic carbon) and dissolved gas composition have been determined on 33 thermal discharges located throughout Sicily (Italy) and its adjacent islands. On the basis of major ion contents, four main water types have been distinguished: (1) a Na-Cl type; (2) a Ca-Mg > Na-SO 4 -Cl type; (3) a Ca-Mg-HCO 3 type and (4) a Na-HCO 3 type water. Most waters are meteoric in origin or resulting from mixing between meteoric water and heavy-isotope end members. In some samples, d 18 O values reflect the effects of equilibrium processes between thermal waters and rocks (positive 18 O-shift) or thermal waters and CO 2 (negative 18 O-shift). Dissolved gas composition indicates the occurrence of gas/ water interaction processes in thermal aquifers. N 2 /O 2 ratios higher than air-saturated water (ASW), suggest the presence of geochemical processes responsible for dissolved oxygen consumption. High CO 2 contents (more than 3000 cc/litre STP) dissolved in the thermal waters indicate the presence of an external source of carbon dioxide-rich gas. TDIC content and d 13 C TDIC show very large ranges from 4.6 to 145.3 mmol/Kg and from )10.0& and 2.8&, respectively. Calculated values indicate the significant contribution from a deep source of carbon dioxide inorganic in origin. Interaction with Mediterranean magmatic CO 2 characterized by heavier carbon isotope ratios (d 13 C CO2 value from )3 to 0& vs V-PDB (CAPASSO et al., 1997, GIAMMANCO et al., 1998INGUAGGIATO et al., 2000) with respect to MORB value and/ or input of CO 2 -derived from thermal decomposition of marine carbonates have been inferred.