The interest in combining membrane operations and solution crystallization is motivated by the aim to develop more efficient crystallization processes. Membranes, with their intrinsic characteristics of efficiency and operational simplicity, high selectivity, and permeability for the transport of specific components, compatibility between different membrane operations in integrated systems, low energetic requirement, good stability under operating conditions and environmental compatibility, easy control and scale-up, and large operational flexibility, represent a technology that well satisfies the concept of the rationalization of chemical productions, leading to significant innovation in both processes and products. Accordingly, membrane technology provides significant improvements in crystallization. This approach has been put in practice in a number of membrane-assisted crystallization (MAC) configurations. The main features of MAC are: