Water Triggered Synthesis of Highly Stable and Biocompatible 1D Nanowire, 2D Nanoplatelet, and 3D Nanocube CsPbBr<sub>3</sub> Perovskites for Multicolor Two-Photon Cell Imaging

Pramanik, Avijit; Patibandla, Shamily; Gao, Ye; Gates, Kaelin; Ray, Paresh Chandra

doi:10.1021/jacsau.0c00038

Cited by 51 publications

(121 citation statements)

References 70 publications

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“…Significant MPA strength, along with good photostability, also makes perovskite materials with great potential for OL, bioimaging and so on. [133,[149][150][151][152][153] As reported by Li et al, the composition of SiO 2 @CsPbBr 3 QDs exhibited 50% OL at 1.68 J cm −2 for the nanosecond regime, and 74% OL at 0.1 J cm −2 for the picosecond regime at 532 nm. [149] Varma et al demonstrated the (BA) 2 (MA)Pb 2 I 7 (I n=2 ) QDs showed more than 50% OL at 85 μJ for 5 ns, 532 nm Neodyminum-doped YttriumAlumini-umGarnet (Nd-YAG) laser pulses.…”

Section: Other Applicationsmentioning

confidence: 89%

“…By taking advantages of significant MPA strength, perovskite materials are desirable for a variety of technological applications. Among them, upconversion lasing, [130,131] sub-band photodetection, [58,132] and high-resolution bioimaging [133,134] have been demonstrated with great potentials for optoelectronic and biophotonic systems.…”

Section: Perovskite-based Mpa Applicationsmentioning

confidence: 99%

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Perovskites: Multiphoton Absorption and Applications

Zhou

Ran

Fan

et al. 2021

Advanced Optical Materials

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critical temperature superconductivity, ferroelectric semiconductor-based cells for solar-energy conversion and others. Analogous to the oxide counterparts, metal lead halide perovskites (MLHPs) (represented by CsPbX 3 , X = I, Br, Cl) also exhibit a cubic lattice in 3Ds at room temperature, as illustrated in Figure 1, but with high-defect tolerance. [9,10] Commonly, their defect tolerance is a major enabling factor for their remarkable optoelectronic properties, such as considerable optical absorption coefficients, long carrier diffusion lengths, and high photoluminescence (PL) efficiency. [11][12][13][14] Furthermore, MLHPs can be synthesized cost effectively on large scales through simple solutionbased processes. As a result, the MLHPs have been investigated for optoelectronic applications in photovoltaics, light-emitting diodes, laser devices, and photodetectors. Recently, the lead halide hybrid organic-inorganic perovskites (HOIPs) have been emerging as a new territory of photovoltaic materials. The HOIPs comprise earth-abundant elements, and yet, exhibit outstanding semiconducting and light-absorption properties. [15,16] In particular, the power-conversion efficiency of HOIP-based devices has surpassed 20% over several years of research and development. [17,18] The HOIPs have a large structural diversity. When the A-site is only occupied by small organic cations (typically methylammonium, MA), they ideally exhibit 3D structures in an octahedral coordination.More interestingly, the HOIPs can exist in layered structures, or 2Ds. 2D HOIPs with unique layered structures are constructed from alternately stacked molecular sheets of organic cations and inorganic anions, as illustrated in Figure 1. The stacking sheets in 2D HOIPs can be regarded as a multiquantum-well structure in semiconductor physics, greatly enhancing the quantum and/or dielectric confinements. As a result, the free charge carriers (electrons or holes) can be strongly confined in atomic-thickness layers, readily forming excitons, which can be treated theoretically as hydrogen-like quasi-particles but moving in 2Ds. As a result, NLO effects can be greatly enhanced along with strong exciton-photon coupling. [19][20][21][22] 2D perovskites have opened up a new opportunity for both fundamental research and practical applications in ultrathin and flexible optoelectronics devices.Moreover, perovskites can also be synthesized into various lower-dimensional structures such as nanocrystals with controllable shapes and sizes. [11,23,24] This allows ones to modulate the quantum confinement effect in the lower-dimensional structures to achieve desirable light-to-electrical conversion, light-emitting, lasing, photodetecting, and NLO properties for various optoelectronic applications.Recently, there have been intensive and extensive research works on perovskites because of their excellent electrical and optical properties. This review is focused on their multiphoton absorption (MPA) and applications. All the MPA coefficients or cross-sections reported in the ...

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Section: Other Applicationsmentioning

confidence: 89%

Section: Perovskite-based Mpa Applicationsmentioning

confidence: 99%

Perovskites: Multiphoton Absorption and Applications

Zhou

Ran

Fan

et al. 2021

Advanced Optical Materials

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“…The record of photoluminescence and electroluminescence efficiency 216 of 2D perovskites has continuously been broken in display, encryption, biological imaging and X-Ray detection. 52,217,218 For instance, Chandra et al 219 reported the use of specific antibody attached water-resistant CsPbBr 3 nanocrystals in different dimensions for two-photon imaging of breast cancer cells in the near IR region, superior to conventional organic fluorescence labels.…”

Section: Perspectivesmentioning

confidence: 99%

Design of two-dimensional halide perovskite composites for optoelectronic applications and beyond

Song

Wang

et al. 2022

Mater. Adv.

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“…A good example of that new emerging application of perovskites is the recent report by Pramanik and co-workers who developed fully biocompatible CsPbBr 3 nanomaterials with different morphologies by coating them with amine-poly(ethylene glycol)-propionic acid. [63] A traditional approach to functionalization of perovskite surface with biocompatible agents would be the exchange of the existing hydrophobic ligands on CsPbBr 3 surface to a biological surfactant along with transfer to the aqueous medium. Instead, a more complex strategy was employed which rests on the synthesis of non-luminescent 0D Cs 4 PbBr 6 NCs using hot injection method, followed by treatment with water of these NCs Adv.…”

Section: Two-photon Imagingmentioning

confidence: 99%

Nonlinear Optical Properties of Emerging Nano‐ and Microcrystalline Materials

Zarȩba

Nyk

Samoć

2021

Advanced Optical Materials

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The activity in the research on novel optical materials exhibiting nonlinear optical (NLO) properties is surveyed, especially nonlinear absorption, that may be attractive for various applications, including those in optoelectronics, photonics, and biophotonics. The recently introduced concept of “NLO pigments”—insoluble colored materials that can exhibit useful NLO effects—is demonstrated to apply to the multifunctional group of coordination polymers (CPs) and their subgroup of metal‐organic frameworks (MOFs), which may be applied in their microcrystalline form or as nanoparticles. Nanocrystalline materials such as semiconductor quantum dots or plasmonic particles made of noble metals have been widely studied and their properties have been often reviewed, thus they are not included in this review. On the other hand, studies performed on perovskites are described: materials that appear to have great potential for NLO applications in addition to their well‐known merit in photovoltaics. There is also much activity in the field of low‐dimensional, especially 2D structures of various kinds, and this review covers many examples of such structures, not including the broad topic of carbon nanostructures (graphene, nanotubes etc.) but concentrating on other emerging nonlinear optical materials such as black phosphorus, transition metal dichalcogenides, MXenes, and topological insulators.

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Water Triggered Synthesis of Highly Stable and Biocompatible 1D Nanowire, 2D Nanoplatelet, and 3D Nanocube CsPbBr₃ Perovskites for Multicolor Two-Photon Cell Imaging

Cited by 51 publications

References 70 publications

Perovskites: Multiphoton Absorption and Applications

Perovskites: Multiphoton Absorption and Applications

Design of two-dimensional halide perovskite composites for optoelectronic applications and beyond

Nonlinear Optical Properties of Emerging Nano‐ and Microcrystalline Materials

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Water Triggered Synthesis of Highly Stable and Biocompatible 1D Nanowire, 2D Nanoplatelet, and 3D Nanocube CsPbBr3 Perovskites for Multicolor Two-Photon Cell Imaging

Cited by 51 publications

References 70 publications

Perovskites: Multiphoton Absorption and Applications

Perovskites: Multiphoton Absorption and Applications

Design of two-dimensional halide perovskite composites for optoelectronic applications and beyond

Nonlinear Optical Properties of Emerging Nano‐ and Microcrystalline Materials

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Water Triggered Synthesis of Highly Stable and Biocompatible 1D Nanowire, 2D Nanoplatelet, and 3D Nanocube CsPbBr₃ Perovskites for Multicolor Two-Photon Cell Imaging