Waterbed inspired stress relaxation strategies of patterned silicon anodes for fast-charging and longevity of lithium microbatteries

Chen, Yi-Xiu; Cheng, Yin-Wei; Huang, Jun-Han; Liu, Chuan-Pu

doi:10.1039/d3ta03968d

J. Mater. Chem. A

2023

DOI: 10.1039/d3ta03968d

|View full text |Cite

Waterbed inspired stress relaxation strategies of patterned silicon anodes for fast-charging and longevity of lithium microbatteries

Yi-Xiu Chen,

Yin-Wei Cheng,

Jun-Han Huang

et al.

Abstract: Over the past 20 years, silicon (Si) has been an attended anode material for lithium-ion batteries due to its high capability. However, the large strain evolution during lithiation/delithiation that leads...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

References 66 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Interface and Morphology Engineered Amorphous Si for Ultrafast Electrochemical Lithium Storage

Sonia,

Haider,

Ghosh

et al. 2024

Small

View full text Add to dashboard Cite

Ultrafast high‐capacity lithium‐ion batteries are extremely desirable for portable electronic devices, where Si is the most promising alternative to the conventional graphite anode due to its very high theoretical capacity. However, the low electronic conductivity and poor Li‐diffusivity limit its rate capability. Moreover, high volume expansion/contraction upon Li‐intake/uptake causes severe pulverization of the electrode, leading to drastic capacity fading. Here, interface and morphology‐engineered amorphous Si matrix is being reported utilizing a few‐layer vertical graphene (VG) buffer layer to retain high capacity at both slow and fast (dis)charging rates. The flexible mechanical support of VG due to the van‐der‐Waals interaction between the graphene layers, the weak adhesion between Si and graphene, and the highly porous geometry mitigated stress, while the three‐dimensional mass loading enhanced specific capacity. Additionally, the high electronic conductivity of VG boosted rate‐capability, resulting in a reversible gravimetric capacity of ≈1270 mAh g−1 (areal capacity of ≈37 µAh cm−2) even after 100 cycles at an ultrafast cycling rate of 20C, which provides a fascinating way for conductivity and stress management to obtain high‐performance storage devices.

show abstract

Interface and Morphology Engineered Amorphous Si for Ultrafast Electrochemical Lithium Storage

Sonia,

Haider,

Ghosh

et al. 2024

Small

View full text Add to dashboard Cite

show abstract

Mechanistic insight into the impact of dry-state prelithiated SiOx thin-film anode toward extremely fast-charging and long-term stability

Chen,

Huang,

Liu

2024

Nano Energy

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Waterbed inspired stress relaxation strategies of patterned silicon anodes for fast-charging and longevity of lithium microbatteries

Abstract: Over the past 20 years, silicon (Si) has been an attended anode material for lithium-ion batteries due to its high capability. However, the large strain evolution during lithiation/delithiation that leads...

Cited by 2 publications

References 66 publications

Interface and Morphology Engineered Amorphous Si for Ultrafast Electrochemical Lithium Storage

Interface and Morphology Engineered Amorphous Si for Ultrafast Electrochemical Lithium Storage

Mechanistic insight into the impact of dry-state prelithiated SiOx thin-film anode toward extremely fast-charging and long-term stability

Contact Info

Product

Resources

About