Waterborne polyurethane as a carbon coating for micrometre-sized silicon-based lithium-ion battery anode material

Abstract

Waterborne polyurethane (WPU) is first used as a carbon-coating source for micrometre-sized silicon. The remaining nitrogen (N) and oxygen (O) heteroatoms during pyrolysis of the WPU interact with the surface oxide on the silicon (Si) particles via hydrogen bonding (Si–OH⋯N and Si–OH⋯O). The N and O atoms involved in the carbon network can interact with the lithium ions, which is conducive to lithium-ion insertion. A satisfactory performance of the Si@N, O-doped carbon (Si@CNO) anode is gained at 25 and 55°C. The Si@CNO anode shows stable cycling performance (capacity retention of 70.0% over 100 cycles at 25°C and 60.3% over 90 cycles at 55°C with a current density of 500 mA g−1) and a superior rate capacity of 864.1 mA h g−1 at 1000 mA g−1 (25°C). The improved electrochemical performance of the Si@CNO electrode is attributed to the enhanced electrical conductivity and structural stability.

Review of the Scalable Core–Shell Synthesis Methods: The Improvements of Li‐Ion Battery Electrochemistry and Cycling Stability

“…[ 205 ] The physical barrier of the carbon shell isolates the contact between silicon and electrolyte, thereby improving the stability of the SEI film. [ 206 ] To address the issue of significant volume changes in silicon electrodes during cycling, Zhi and colleagues proposed a new design for skin‐like covalent encapsulation of silicon electrodes. This methodology is described as 2D covalent encapsulation using chemical vapor deposition (CVD), as illustrated in Figure a.…”