1-x) (Al 0.2 La 0.8 TiO 3 ) ? (x) (CuTiO 3 ) (x = 0.2-0.8) [ALTCT] nanocomposites were prepared through hydrothermal process. The diffraction study indicated the formation of tetragonal structure expressing maximum intense peak at * 25.586 o for all samples. Lattice constants a = b and c values were found to be increasing from 3.774 to 3.780 A ˚, and 9.394-9.950 A ˚, respectively as a function of 'x'. The surface morphology showed that the formation of nanospheres, and hexagonal nanorods. Further, the dielectric behavior was studied, and the results showed space charge effect, dielectric relaxation dynamics, and frequency-dependent dielectric properties. Impedance and dielectric modulus formalism was carried out to elucidate the microstructure, polarization, and electrical conduction mechanism.