The energy eigenvalues and eigenfunctions of a core–shell CdSe/ZnS quantum dot structure
have been obtained under an effective-mass approximation. The electric transition dipole
moment induced by the 1s (inside the well)–1s (outside the well) transition has been
calculated. The optical nutation signal induced by the transition has been calculated
numerically based on the optical Bloch equations. In particular, the influence of the size
variation of the core’s radius and the shell’s thickness has been studied. It has been shown
from the results that the optical nutation signal is sensitive to the size and structure, and
that there is an optimal structure and size for the optical nutation phenomenon. The
quantum size dependent Rabi frequency and intensity of the optical nutation are also
discussed.