The water quality of rivers worldwide is of persistent interest due to its impact on human life. Five streamwater quality parameters of Suceava River were monitored in 2019 upstream and downstream of Suceava city, Romania: dissolved oxygen, specific conductivity, pH, oxidation-reduction potential, and temperature. Data was recorded at a high temporal frequency, every hour, and produced Water Quality Index (WQI) time series of similar resolution. Our additive WQI has variants with particular advantages. Water quality of Suceava city exhibits a diurnal cycle. Upstream, WQI values indicate a quasi-permanent good water quality; downstream, the water quality oscillates around the average WQI value because of the various sources of water contaminants, especially the wastewaters from the wastewater treatment plant. Parameters from this point source of pollution are taken into account to explain the decaying streamwater quality towards the end of 2019. WQI is useful for detecting time intervals when water self-purification events have a high chance of occurrence.