Comparative studies of wear resistance during dry friction of vacuum ion-plasma coatings of nitride systems TiAlN and CrAlSiN are carried out. The structural parameters, coating thickness, and physical and mechanical properties were chosen as comparison parameters. A fundamental difference in the wear mechanisms of the coatings is demonstrated. In the TiAlN-system coatings develop an oxidative wear mechanism due to their insufficient heat resistance. The CrAlSiN-system coatings have maximum resistance to plastic deformation. And they are wear out according to the fatigue mechanism, which is typical for coatings with a high level of mechanical properties.