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Purpose of research. Study of the structure and properties of powders obtained by electroerosion of the LS58-3 alloy in a carbon-containing medium - isopropyl alcohol.Methods. The process of electrical erosion of LS58-3 alloy waste was carried out on a patented installation, LS58-3 alloy waste was used as metal waste. Isopropyl alcohol, which is a carbon-containing medium, was chosen as the working fluid.Studies of the morphology and granulometric composition of the obtained particles were carried out on an electron-ion scanning microscope "Quanta 600 FEG" and a laser particle size analyzer Analysette 22 NanoTec", respectively.X-ray spectral microanalysis of powders was carried out on an energy-dispersive X-ray analyzer from EDAX (Netherlands) built into a scanning electron microscope QUANTA 200 3D (Netherlands). The phase analysis of the powders was performed on a Rigaku Ultima IV X-ray diffractometer (Japan).Results. An analysis of the morphology of the obtained powders showed that the particles are mainly spherical and elliptical in shape, as well as agglomerates.Analysis of the particle size distribution of the powder obtained using the Analysette 22 NanoTec particle size analyzer showed that the average particle size is 24 µm. This particle size was obtained in the operating mode of the installation, in which the electroerosion process proceeds stably.Analysis of the elemental composition has established that free carbon is contained on the surface of the powder particles. The remaining chemical elements Cu, Zn, Pb, Sn are distributed relatively evenly. The presence of free carbon is due to the chemical composition of the dispersion medium, which is carbon-containing.X-ray diffraction analysis of the obtained powders showed the presence of Cu3Zn, Pb, ZnO, CuO2, SnO2 phases. There are no carbide-forming elements in the composition of the alloy.It has been experimentally established that the composition, structure and properties of the charge of LS58-3 brass dispersed by electroerosion are affected by the chemical composition of the working fluid, as well as the dispersion modes.Conclusion. On the basis of the conducted experimental studies, it can be concluded that the use of electroerosive dispersion technology for the processing of LS58-3 brass waste and the production of powders based on it is relevant. It is noted that the particles of the resulting charge have a given set of properties and can be used by various methods of powder metallurgy.
Purpose of research. Study of the structure and properties of powders obtained by electroerosion of the LS58-3 alloy in a carbon-containing medium - isopropyl alcohol.Methods. The process of electrical erosion of LS58-3 alloy waste was carried out on a patented installation, LS58-3 alloy waste was used as metal waste. Isopropyl alcohol, which is a carbon-containing medium, was chosen as the working fluid.Studies of the morphology and granulometric composition of the obtained particles were carried out on an electron-ion scanning microscope "Quanta 600 FEG" and a laser particle size analyzer Analysette 22 NanoTec", respectively.X-ray spectral microanalysis of powders was carried out on an energy-dispersive X-ray analyzer from EDAX (Netherlands) built into a scanning electron microscope QUANTA 200 3D (Netherlands). The phase analysis of the powders was performed on a Rigaku Ultima IV X-ray diffractometer (Japan).Results. An analysis of the morphology of the obtained powders showed that the particles are mainly spherical and elliptical in shape, as well as agglomerates.Analysis of the particle size distribution of the powder obtained using the Analysette 22 NanoTec particle size analyzer showed that the average particle size is 24 µm. This particle size was obtained in the operating mode of the installation, in which the electroerosion process proceeds stably.Analysis of the elemental composition has established that free carbon is contained on the surface of the powder particles. The remaining chemical elements Cu, Zn, Pb, Sn are distributed relatively evenly. The presence of free carbon is due to the chemical composition of the dispersion medium, which is carbon-containing.X-ray diffraction analysis of the obtained powders showed the presence of Cu3Zn, Pb, ZnO, CuO2, SnO2 phases. There are no carbide-forming elements in the composition of the alloy.It has been experimentally established that the composition, structure and properties of the charge of LS58-3 brass dispersed by electroerosion are affected by the chemical composition of the working fluid, as well as the dispersion modes.Conclusion. On the basis of the conducted experimental studies, it can be concluded that the use of electroerosive dispersion technology for the processing of LS58-3 brass waste and the production of powders based on it is relevant. It is noted that the particles of the resulting charge have a given set of properties and can be used by various methods of powder metallurgy.
Purpose. Establishment of the elemental and quantitative composition of alloys - components of road milling cutters, which are used as working bodies for milling the road surface, by X-ray fluorescence analysis.Methods. To establish the chemical composition of alloys - components of cutters of a road milling cutter, WIRTGENW6/20X cutters and their domestic counterpart KZTS A6/20 were studied. The X-ray fluorescence method was chosen to study the elemental composition of the components of the road milling cutters. This method, based on the interaction of X-ray radiation with the analyzed substance, is the most effective and efficient method of analysis, which allows obtaining complete and reliable information about the elemental composition of complex samples in a minimum period of time without destroying them, while maintaining all the physicochemical properties, as well as without using a reference sample. The method is based on the correlation between the X-ray fluorescence intensity and the element concentration in the sample. As a result of irradiating the sample with an X-ray flux, a characteristic emission of atoms is created, which is proportional to their concentration in the sample. With the help of an express analyzer of metals and alloys - the Niton GOLDD spectrometer, experimental data were obtained on the composition of alloys - components of cutters of a road milling machine.Results. During the study, it was revealed that the components of the cutters are made from the following alloys:1. Cutter WIRTGEN W6/20X:- tip made of hard sintered alloy VK8;- housing made of structural alloyed steel 32G2;- spring sleeve of the cutter made of structural carbon steel 08ps;- washer made of structural quality carbon steel 60.2. Cutter KZTS A6/20:- tip made of hard sintered alloy VK8;- housing made of structural alloyed steel 38XV;- spring sleeve made of structural quality carbon steel 40;- washer made of structural alloyed steel 45G.Conclusion. The obtained research results can be used for subsequent processes of hardening or restoration of cutters of road milling machines.
Purpose of research. Optimization of the technological process of dispersing brass waste in a carbon-containing environment by setting up a full factorial experiment.Methods. The electroerosion process of LS58-3 alloy waste was carried out on a patented device, LS58-3 alloy waste (GOST 15527-2004) was used as metal waste. Isopropyl alcohol (GOST 9805-84), which is a carbon-containing medium, was chosen as the working fluid (dispersing medium).Variable parameters during operation of the installation were: the voltage supplied to the electrodes (100...200 V); capacity of discharge capacitors (25...65 μF); discharge frequency 50...100 Hz.When an electric discharge occurs, the electrodes and wastes are instantly destroyed and the smallest powder particles are formed. The granulometric composition of the obtained powder was carried out using the Analysette 22 NanoTec particle size analyzer. The development of a mathematical model of the process of obtaining lead brass powder was carried out by conducting a full factorial experiment of type 23.Results. As a result of mathematical calculations, the maximum value of the optimization output parameter (average particle size) was determined, which was 23.8 μm at the following values of the factors (dispersion modes): the voltage supplied to the electrodes is 200 V, the discharge frequency is 100 Hz, and the capacity of the discharge capacitors is 65 μF.Conclusion. On the basis of the obtained results of studies and calculations, it is possible to conclude that by changing the operating modes of the EDM installation, it is possible to obtain powders of different sizes. The voltage applied to the electrodes and the capacity of the discharge capacitors have the greatest influence on the particle size of the resulting charge. When the values of these parameters increase, the mass yield of the powder increases, which directly depends on the size of the obtained particles.The obtained regression equation makes it possible to determine at which operating modes of the installation it is possible to obtain powder of a given particle size.
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