“…To overcome these limitations, electrochemical techniques have attracted much attention that offers the convenient detection of toxic metals, advantages of minimal sample pretreatment, economics, rapid ease of detection, robustness, and portability. 15,16 As we all know, differential pulse voltammetry (DPV), cyclic voltammetry (CV), linear sweep voltammetry (LSV), and electrochemical impedance spectroscopy have been employed for the sensitive determination of trace metal ions in different environment samples. 17,18 However, the electrochemical activity of glassy carbon electrodes (GCE) has poor selectivity, sensitivity, and repeatability to real samples as a result of delayed charge transfer kinetics, interference of coexisting metal ions, and low catalytic activity.…”