The objective of this study was to investigate how weld overlays with nickel superalloys are important for the integrity, due the high temperatures and corrosive environments that can be experienced in mineral processing environments, of mining and processing equipment. The Ni-Cr-Mo superalloy Inconel 686 overlays are fabricated through automatic gas metal arc welding with variations in arc voltage and travel speed (i.e., heat input), and they have overlap between adjacent weld tracks for applications in the mining and minerals sector. The impact of variations in the process parameters and the size of the weld overlapping on the dilution, solidification morphology, microsegregation, and microhardness were investigated. Both geometric and chemical composition definitions were used to quantify the extent of the weld dilution. Subsequently, the weld geometry and dilution were correlated with the solidification microstructure and phase transformations. The maximum dilutions were measured to be 13.63% (1/2 overlap, 5.96 kJΒ·cmβ1) and 15.39% (1/3 overlap, 4.77 kJΒ·cmβ1), which shows that less of an overlap increases the dilution level. Scanning electron microscopy and chemical composition analysis revealed that an increase in weld heat input and dilution level led to higher levels of microsegregation for Mo and Cr, as well as the volume fraction of Mo- and Cr-rich phases in the interdendritic/intercellular regions in the overlay layer. Analysis of the weld overlays in the current study revealed strong and unprecedented connections between the weld overlay process conditions, the resultant metallurgy (i.e., dendrite arm spacing, microsegregation, and phase formation), and the hardness of the overlay. It was concluded that the optimal weld overlays in the processing window studied in this investigation were fabricated at mid-level heat inputs (i.e., 4β5 kJΒ·cmβ1) and a 1/2 track overlap.