Well-defined fluoro- and carbazole-containing diblock copolymers: synthesis, characterization and immobilization onto Au-coated silicon surfaces

Savva, Ioanna; Demetriou, Maria; Othonos, Andreas; Turcu, Rodica; Popa, Adriana; Macavei, Sergiu; Krasia‐Christoforou, Theodora

doi:10.1039/c2ra20650a

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“…A series of well-defined diblock copolymers consisting of 2-(N-carbazolyl)ethyl methacrylate (CbzEMA) and 2,2,3,3,4,4,4-heptafluorobutyl methacrylate (HFBMA) (CbzEMA x -b-HFBMA y ) was synthesized by Reversible Addition-Fragmentation chain Transfer (RAFT) controlled radical polymerization [33]. The RAFT process allows for the preparation of functional polymeric materials characterized by pre-determined molecular weights, narrow molecular weight distributions and pre-defined architectures [34,35].…”

Section: Methodsmentioning

confidence: 99%