Wet milling synthesis of ammonium cobalt phosphate hydrate platelets for LCP‐olivine cathodes of LIBs using a bead mill

Abstract

In this study, NH4CoPO4·H2O (ACP) platelets were synthesized from NH4H2PO4 and Co(OH)2 by wet milling process using a bead mill. ACP is one of the precursors of LiCoPO4 (LCP) cathode materials for Li‐ion batteries. In the wet milling, ACP large platelets were synthesized in a short time at the beginning, and the large platelets were gradually cleaved into the smaller platelets. The lateral sizes of the ACP platelets were several 10 μm at 30 min and about 10 μm at 5 h. It was found that the ACP platelets were synthesized efficiently by using the bead mill as a promising machine for the scale‐up in manufacturing. The ACP platelets were converted into LCP by mixing with Li2CO3 and heating, whereas platelet shapes were retained. The initial discharge capacities of the cathodes using the LCP platelets converted from the ACP of 30 min and 5 h milling were 70 and 95 mAh/g at 0.05 C, respectively. It is because the specific surface area of the latter sample (3.3 m2/g) was larger than that of the former (2.2 m2/g). The larger specific surface area possibly led to the increase of contacts with electron conductive additives (carbon) and electrolytes.

Hydrothermal synthesis of dittmarite-group NH4(Co1−xMnx)PO4·H2O particles as inorganic violet pigments

“…The compositional control of dittmarite-group NH 4 (Co 1−x Mn x )PO 4 $H 2 O phase would be useful for researchers in not only pigment but also many other material elds such as catalysts, 8,9 capacitors, 12-14,24,25 magnetic devises 23 and electrodes for Li-ion batteries. 10,11,26,27 In this work, we prepared NH 4 (Co 1−x Mn x )PO 4 $H 2 O particles via a hydrothermal route and evaluated their colour variation with the replacement of Co 2+ ions by Mn 2+ ions to different degrees. The binary dittmarite-group compounds were obtained from aqueous solutions containing MnCl 2 $4H 2 O, CoCl 2 $6H 2 O, and (NH 4 ) 2 HPO 4 by hydrothermal treatment.…”

“…The compositional control of dittmarite-group NH 4 (Co 1− x Mn x )PO 4 ·H 2 O phase would be useful for researchers in not only pigment but also many other material fields such as catalysts, 8,9 capacitors, 12–14,24,25 magnetic devises 23 and electrodes for Li-ion batteries. 10,11,26,27…”

“…77362 PV49). 4 In recent years, NH 4 CoPO 4 $H 2 O has also been investigated as an electrocatalyst for the oxygen evolution reaction, 8,9 a precursor of LiCoPO 4 cathode materials for Li-ion batteries, 10,11 and a highperformance supercapacitor. [12][13][14] Accordingly, ammonium cobalt phosphate materials have drawn extensive research attention.…”