When porphyrins meet 2D materials: spectroscopic and photocatalytic properties

Lindner, Aleksandra; Lesniewicz, Aleksandra; Kolman, Aleksander; Larowska-Zarych, Daria; Marciniak, Bronislaw; Lewandowska-Andralojc, Anna

doi:10.1039/d4tc00416g

J. Mater. Chem. C

2024

DOI: 10.1039/d4tc00416g

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When porphyrins meet 2D materials: spectroscopic and photocatalytic properties

Aleksandra Lindner,

Aleksandra Lesniewicz,

Aleksander Kolman

et al.

Abstract: Exploring the fundamental understanding of the structure–property–performance relationship of porphyrins functionalized with 2D materials.

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Recent Advances in Bonding Regulation of Metalloporphyrin‐Modified Carbon‐Based Catalysts for Accelerating Energy Electrocatalytic Applications

Lu,

Li,

Fan

et al. 2024

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Metalloporphyrins modified carbon‐based materials, owing to the excellent acid‐base resistance, optimal electron transfer rates, and superior catalytic performance, have shown great potential in energy electrocatalysis. Recently, numerous efforts have concentrated on employing carbon‐based substrates as platforms to anchor metalloporphyrins, thereby fabricating a diverse array of composite catalysts tailored for assorted electrocatalytic processes. However, the interplay through bonding regulation of metalloporphyrins with carbon materials and the resultant enhancement in catalyst performance remains inadequately elucidated. Gaining an in‐depth comprehension of the synergistic interactions between metalloporphyrins and carbon‐based materials within the realm of electrocatalysis is imperative for advancing the development of innovative composite catalysts. Herein, the review systematically classifies the binding modes (i.e., covalent grafting and non‐covalent interactions) between carbon‐based materials and metalloporphyrins, followed by a discussion on the structural characteristics and applications of metalloporphyrins supported on various carbon‐based substrates, categorized according to their binding modes. Additionally, this review underscores the principal challenges and emerging opportunities for carbon‐supported metalloporphyrin composite catalysts, offering both inspiration and methodological insights for researchers involved in the design and application of these advanced catalytic systems.

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Recent Advances in Bonding Regulation of Metalloporphyrin‐Modified Carbon‐Based Catalysts for Accelerating Energy Electrocatalytic Applications

Lu,

Li,

Fan

et al. 2024

Small

View full text Add to dashboard Cite

show abstract

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When porphyrins meet 2D materials: spectroscopic and photocatalytic properties

Abstract: Exploring the fundamental understanding of the structure–property–performance relationship of porphyrins functionalized with 2D materials.

Cited by 1 publication

References 190 publications

Recent Advances in Bonding Regulation of Metalloporphyrin‐Modified Carbon‐Based Catalysts for Accelerating Energy Electrocatalytic Applications

Recent Advances in Bonding Regulation of Metalloporphyrin‐Modified Carbon‐Based Catalysts for Accelerating Energy Electrocatalytic Applications

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