Electrical discharge machining (EDM) is considered suitable for machining materials that are extremely hard or strong, and are wear or temperature resistant. In Chap. 2, we outline EDM characteristics of carbon fiber-reinforced carbon composites and AISI D2 tool steel. This article is organized as follows: first, the effects of EDM processing variables on delamination, the recast layer, surface roughness, and material removal rate (MRR) of carbon fiber-reinforced carbon composites are presented. Rotation of the workpiece allows fresh dielectric material to enter for effective spark discharge, and to provide better machining performance. Therefore, the second section of this chapter is devoted to a study of the effects of rotary EDM parameters on MRR and surface roughness of AISI D2 tool steel. The EDM process produces a damaged layer with different mechanical behaviors from those of the base metal. An understanding of the strength of an EDM sample is required. The third section describes an investigation of EDM AISI D2 tool steel surface characteristics and machining damage. EDM damage was studied using a new damage variable. An understanding of the surface texture of EDM specimens on the nanoscale is required. In the fourth section, surface morphology, surface roughness, and micro-cracks of AISI D2 tool steel machined by the EDM process were analyzed by atomic force microscopy (AFM). Experimental results show that the thickness of the recast layer, micro-crack depth, surface roughness, and residual tensile stress increase with the increase in power input. The EDM process effectively produces excellent surface characteristics in specimens, under low discharge energy conditions.