2008
DOI: 10.1002/pat.1115
|View full text |Cite
|
Sign up to set email alerts
|

White‐light emission from mixing blue and red‐emitting metal complexes

Abstract: Combining polymeric architectures with metal ions produces hybrid materials with extremely rich properties. We have been studying polymers containing terpyridine in the side chain. This report discusses a novel white‐light emission from a two‐emitter system comprising a blue‐emitting dysprosium‐chelated polymer and a red‐emitting ruthenium complex. The polymer architecture easily allows the incorporate of blue color into the material and provides a matrix which leads to the facile production of truly white lig… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
4
1

Citation Types

0
24
0

Year Published

2010
2010
2017
2017

Publication Types

Select...
7
1

Relationship

0
8

Authors

Journals

citations
Cited by 39 publications
(24 citation statements)
references
References 47 publications
0
24
0
Order By: Relevance
“…Among functional groups that can be introduced in polymer side-chains, the terpyridine ligand is of particular interest [ 61 ], mostly due to its high binding affinity for transition metal ions [ 62 , 63 ] and excellent luminescence resulting notably from the binding with lanthanide ions [ 64 , 65 ]. Hence, the syntheses of terpyridine side-chain functionalized acrylate [ 66 ], methacrylate [ 56 , 67 , 68 , 69 , 70 ], acrylamide [ 58 , 71 , 72 ] and styrenic [ 55 , 73 , 74 , 75 ] copolymers have been reported during the past few years. In the presence of transition metal ions, the same copolymers have been further self-assembled into dry or swollen networks where macromolecular chains are held together by metal-ligand bridges [ 56 , 58 , 60 , 66 , 70 , 72 , 75 ].…”
Section: Introductionmentioning
confidence: 99%
“…Among functional groups that can be introduced in polymer side-chains, the terpyridine ligand is of particular interest [ 61 ], mostly due to its high binding affinity for transition metal ions [ 62 , 63 ] and excellent luminescence resulting notably from the binding with lanthanide ions [ 64 , 65 ]. Hence, the syntheses of terpyridine side-chain functionalized acrylate [ 66 ], methacrylate [ 56 , 67 , 68 , 69 , 70 ], acrylamide [ 58 , 71 , 72 ] and styrenic [ 55 , 73 , 74 , 75 ] copolymers have been reported during the past few years. In the presence of transition metal ions, the same copolymers have been further self-assembled into dry or swollen networks where macromolecular chains are held together by metal-ligand bridges [ 56 , 58 , 60 , 66 , 70 , 72 , 75 ].…”
Section: Introductionmentioning
confidence: 99%
“…Several strategies, such as generation in situ, surfactant encapsulation, or functionalization with a polymerizable monomer unit(s) have been explored to avoid these problems. [1] Although a wide plethora of examples can be found in which quantum dots, [2] ZnO, [3] polyoxometalate, [4] or rare-earth cations [5] are incorporated into polymers to act as emitting phosphors, there is a lack of Abstract: The embedding of functional inorganic entities into polymer matrices has become an intense field of investigation in which the main challenges are to keep the added value of the inorganic entities while preventing their self-aggregation within the organic matrix. We present a simple way to obtain a homogeneous highly red-NIR luminescent hybrid copolymer that contains covalently bonded nanometric-sized {Re 6 cluster complexes are primarily functionalized in two steps with tert-butylpyridine (TBP) and methacrylic acid (MAC) to give neutral [Re 6 Se 8 A C H T U N G T R E N N U N G (TBP) 4 A C H T U N G T R E N N U N G (MAC) 2 ] building blocks that are copolymerized with methyl methacrylate (MMA) either in solution or in bulk in the presence of azobisisobutyronitrile as an initiator.…”
Section: Introductionmentioning
confidence: 99%
“…[ 9 ] However, with expanding tunable optical applications, multicolor white light-emitting materials are in growing demand since in comparison to monochromic emission multichromic white light emission will enable more sensitive multistimuli responsive materials. [ 10 ] Despite a variety of research efforts in organic-based materials, [ 11 ] copolymerbased metal-supported compounds [ 12 ] and metal complexes in the solid, [ 13 ] solution, [ 14 ] and gel state, [ 15 ] examples of stimuliresponsive white luminescent materials are still few.…”
Section: Doi: 101002/adom201400493mentioning
confidence: 99%