The quantum transition between shifted zero-mode wave functions is shown to be induced by the systematic deformation of topological and non-topological defects that support the 1-dim doublewell (DW) potential tunneling dynamics. The topological profile of the zero-mode ground state, ψ 0 , and the first excited state, ψ 1 , of DW potentials are obtained through the analytical technique of topological defect deformation. Deformed defects create two inequivalent topological scenarios connected by a symmetry breaking that support the quantum conversion of a zero-mode stable vacuum into an unstable tachyonic quantum state. Our theoretical findings reveal the topological origin of two-level models where a non-stationary quantum state of unitary evolution, ψ 0 +e −iE t ψ 1 , that exhibits a stable tunneling dynamics, is converted into a quantum superposition involving a self-vanishing tachyonic mode, e −E t ψ 0 + ψ 1 , that parameterizes a tunneling coherent destruction.The non-classical nature of the symmetry breaking dynamics is recreated in terms of the single particle quantum mechanics of 1-dim DW potentials.