“…It is suggested that the surface dipole moment potential depends on the density of the surface atoms, while the work function value increases as the surface atomic density increases [58]. In fact, it is reported that the work function decreases as a function of surface step density [59], which can be explained by the Smoluchowski effect [60,61]. Indeed, the minimum work function observed on Si nanoparticles can also be explained by this same effect.…”