X-Ray Investigations of the Tin-Phosphorus System.

In Situ EXAFS‐Derived Mechanism of Highly Reversible Tin Phosphide/Graphite Composite Anode for Li‐Ion Batteries

“…[33,34] The built-in AUTOBK algorithm was used to minimize background below R bkg = 1.0 Å. EXAFS data of OCV and lithiated/delithiated states merged from 8-16 scans, were modeled in Artemis using FEFF6 theoretical models for metallic β-Sn metal, [25] SnO 2 , [24] Sn 4 P 3 , [21] and quick first shell theory for SnLi paths. [33,34] The built-in AUTOBK algorithm was used to minimize background below R bkg = 1.0 Å. EXAFS data of OCV and lithiated/delithiated states merged from 8-16 scans, were modeled in Artemis using FEFF6 theoretical models for metallic β-Sn metal, [25] SnO 2 , [24] Sn 4 P 3 , [21] and quick first shell theory for SnLi paths.…”

Novel Compounds Sn10In14P22I8 and Sn14In10P21.2I8 with Clathrate I Structure: Synthesis and Crystal and Electronic Structure

“…The parameters of the second doublet resemble those recorded from Sn P for which the values of "2.54 and "0.46 mm s\ were obtained (23). There are two di!erent tin sites in the layered structure of Sn P (24). In both of them, tin forms three short (2.66}2.73 A s ) bonds with phosphorus within the same layer and distant bonds with either three tin (3.25 A s ) or three phosphorus (2.97 A s ) atoms of the neighboring layer.…”

Na1−xSn2P2 as a new member of van der Waals-type layered tin pnictide superconductors

“…Besides, the sister compound SrSn 2 As 2 , having a crystal structure analogous to NaSn 2 As 2 , has been theoretically suggested to be very close to the topological critical point, hosting three-dimensional Dirac state at the Fermi level 11 , which was experimentally investigated by angle-resolved photoemission spectroscopy 12 . There are various structural analogues with conducting tin-pnictide (SnPn) layers, including Sn 4 Pn 3 13,14 and ASnPn 15–19 , as well as ASn 2 Pn 2 9,10,12,20–22 , where A denotes alkali or alkaline earth metal (see Fig. 1).…”