2012
DOI: 10.1134/s0031918x12040072
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X-ray photoelectron spectroscopy of ceramic composites Bi,Pb-2223/Ag annealed in an atmosphere with a reduced content of oxygen (7.5% O2 + 92.5% N2)

Abstract: X ray photoelectron spectroscopy (XPS) has been used to study (001) textured ceramic compos ites Bi,Pb 2223/Ag after high temperature annealing in an atmosphere with a reduced oxygen content (7.5% O 2 + 92.5% N 2 ). Discussion is performed of the chemical and charge states of heavy atoms (Bi, Pb, Sr, Ca, Cu) and light atoms (of the main element (oxygen) and impurity element (carbon)) under conditions of oxygen deficit in the lattice.

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“…[ 32 ] Two new peaks at 368.1 and 374.1 eV appear in the AgNPs‐MOGs xerogel, which can be attributed to Ag 3d 5/2 and Ag 3d 3/2 , respectively, consistent with references. [ 33 ] The peaks at 368.1 and 367.6 eV correspond to Ag 0 , while the peaks at 374.1 and 373.4 eV correspond to Ag 2 O (Figure 2e). The area of Ag 0 was significantly higher than that of Ag + , indicating that only a small amount of Ag 2 O was generated owing to the encapsulation of the sheath TPE to isolate the core AgNPs‐MOGs from the air (Figure 2f and Figure S7, Supporting Information).…”
Section: Resultsmentioning
confidence: 99%
“…[ 32 ] Two new peaks at 368.1 and 374.1 eV appear in the AgNPs‐MOGs xerogel, which can be attributed to Ag 3d 5/2 and Ag 3d 3/2 , respectively, consistent with references. [ 33 ] The peaks at 368.1 and 367.6 eV correspond to Ag 0 , while the peaks at 374.1 and 373.4 eV correspond to Ag 2 O (Figure 2e). The area of Ag 0 was significantly higher than that of Ag + , indicating that only a small amount of Ag 2 O was generated owing to the encapsulation of the sheath TPE to isolate the core AgNPs‐MOGs from the air (Figure 2f and Figure S7, Supporting Information).…”
Section: Resultsmentioning
confidence: 99%