Untitled

Hayami, Shinya; Kawahara, Takayoshi; Juhász, G.; Kawamura, Kazunori; Uehashi, Keigo; Sato, Osamu; Maeda, Yonezo

doi:10.1023/a:1022503609539

Cited by 33 publications

(16 citation statements)

References 11 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…This unusual hysteresis loop involving a two-step spin crossover in the warming mode and a one-step transition in the cooling mode could be simulated theoretically [135]. Solvent removal from [Fe(qsal) 2 ]NCSe•2DMSO leads to a transition with an hysteresis loop of width 76 K (T 1/2 "=285 K, T 1/2 #=209 K), which is one of the broadest hysteresis effects reported so far for spin crossover compounds [136] [136] (Table 3). These revealed intermolecular p-interactions between quinoline and phenyl rings resulting in a twodimensional network.…”

Section: Complexes Of Tridentate N 2 O-donating Ligandsmentioning

confidence: 82%

“…However, the magnetic moment determined at room temperature increases with time. Ten days after preparation the sample shows spin crossover with a pronounced hysteresis loop (DT 1/2 =70 K) centred at 286 K. These interesting spin crossover features prompted the study of the selenocyanate salts [135,136] [136] are low spin at room temperature. However, these all lose solvent molecules on heating, converting to the non-solvated high spin analogues which display spin crossover below room temperature.…”

Section: Complexes Of Tridentate N 2 O-donating Ligandsmentioning

confidence: 99%

See 1 more Smart Citation

Iron(III) Spin Crossover Compounds

Koningsbruggen

Maeda

Oshio

2004

Topics in Current Chemistry

175

130

View full text Add to dashboard Cite

In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-b-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.

show abstract

Section: Complexes Of Tridentate N 2 O-donating Ligandsmentioning

confidence: 82%

Section: Complexes Of Tridentate N 2 O-donating Ligandsmentioning

confidence: 99%

Iron(III) Spin Crossover Compounds

Koningsbruggen

Maeda

Oshio

2004

Topics in Current Chemistry

175

130

View full text Add to dashboard Cite

show abstract

“…Combining SC and electrical conductivity was the aim of Dorbes et al [11] [12]. Analogously, similar properties have been studied on the salts of the [Fe(qsal) 2 ] + and Fe(R-salEen)] + complex cations as well [13][14][15][16][17][18][19].…”

Section: Introductionmentioning

confidence: 97%

Temperature and pressure effects on the spin state of ferric ions in the [Fe(sal2-trien)][Ni(dmit)2] spin crossover complex

Szilágyi¹,

Dorbes²,

Molnár³

et al. 2008

Journal of Physics and Chemistry of Solids

View full text Add to dashboard Cite

This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting galley proof before it is published in its final citable form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. A c c e p t e d m a n u s c r i p t

show abstract

“…1a)[18] and[Fe(pap) 2 ]X·solv (X = NO 3 , BPh 4 , PF 6 , ClO 4 , NCS) are strongly dependent on counter anions and/or solvent molecules. [Fe(qsal) 2 ]Cl·2H 2 O shows incomplete SCO, while [Fe(qsal) 2 ]Br·H 2 O and [Fe(qsal) 2 ]I are HS and LS complexes, respectively [19].…”

mentioning

confidence: 99%